物理化学学报 >> 2011, Vol. 27 >> Issue (08): 1859-1862.doi: 10.3866/PKU.WHXB20110801

电化学和新能源 上一篇    下一篇

噻二嗪衍生物的合成及Pb2+在水/1,2-二氯乙烷界面转移的电化学性质

BASLAK Canan, BINGOL Haluk, COSKUN Ahmet, ATALAY Tevfik   

  1. Department of Chemistry, Selcuk University, 42099 Meram/Konya, Turkey
  • 收稿日期:2011-03-14 修回日期:2011-05-30 发布日期:2011-07-19
  • 通讯作者: ATALAY Tevfik E-mail:tatalay51@gmail.com
  • 基金资助:

    The project was supported by the Scientific Research Fund of Selcuk University, Turkey (BAP-07201027).

Synthesis of a Novel Thiadiazine Derivative and Electrochemical Properties for Pb2+ Transfer across Water/1,2-Dichloroethane Interface

BASLAK Canan, BINGOL Haluk, COSKUN Ahmet, ATALAY Tevfik   

  1. Department of Chemistry, Selcuk University, 42099 Meram/Konya, Turkey
  • Received:2011-03-14 Revised:2011-05-30 Published:2011-07-19
  • Contact: ATALAY Tevfik E-mail:tatalay51@gmail.com
  • Supported by:

    The project was supported by the Scientific Research Fund of Selcuk University, Turkey (BAP-07201027).

摘要:

The transfer of Pb2+ facilitated by interfacial complexation with 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine (PPTA) at the polarized water/1,2-dicholoroethane (1,2-DCE) interface was investigated by cyclic voltammetry. We synthesized the thiadiazine derivative, PPTA, firstly. The transfer was performed at different metal concentrations and scan rates, and the obtained voltammetric transfer peaks toward Pb2+ ion over other divalent cations (Zn2+, Co2+, Ni2+, Cd2+, Hg2+, and Cu2+) were reversible. The dependence of the half-wave potentials of the Pb2+ ion on the concentration of PPTA in the organic phase indicates that the ion transfer is facilitated by the formation of 1:2 (metal:ligand) complex in the organic phase with the association constant (lgβ2) of (17.1±0.2).

关键词: Pb2+, Thiadiazine, Cyclic voltammetry, Ion transfer, ITIES

Abstract:

The transfer of Pb2+ facilitated by interfacial complexation with 5-(4-phenoxyphenyl)-6H-1,3,4-thiadiazin-2-amine (PPTA) at the polarized water/1,2-dicholoroethane (1,2-DCE) interface was investigated by cyclic voltammetry. We synthesized the thiadiazine derivative, PPTA, firstly. The transfer was performed at different metal concentrations and scan rates, and the obtained voltammetric transfer peaks toward Pb2+ ion over other divalent cations (Zn2+, Co2+, Ni2+, Cd2+, Hg2+, and Cu2+) were reversible. The dependence of the half-wave potentials of the Pb2+ ion on the concentration of PPTA in the organic phase indicates that the ion transfer is facilitated by the formation of 1:2 (metal:ligand) complex in the organic phase with the association constant (lgβ2) of (17.1±0.2).

Key words: Pb2+, Thiadiazine, Cyclic voltammetry, Ion transfer, ITIES