芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变

doi:10.3866/PKU.WHXB201203291

物理化学学报 >> 2012, Vol. 28 >> Issue (06): 1418-1424.doi: 10.3866/PKU.WHXB201203291

芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变

焦体峰^1,2, 刘鸣华²

1. 燕山大学环境与化学工程学院, 河北省应用化学重点实验室, 河北秦皇岛 066004;
2. 中国科学院化学研究所, 胶体、界面与化学热力学院重点实验室, 北京 100190

收稿日期:2012-03-09 修回日期:2012-03-28 发布日期:2012-05-17
通讯作者: 焦体峰, 刘鸣华 E-mail:tfjiao@ysu.edu.cn; liumh@iccas.ac.cn
基金资助:
国家自然科学基金(20903078), 中国博士后科学基金(2011M500540), 河北省留学回国人员科技择优资助经费(2011052)和河北省高校百名优秀创新人才支持计划(CPRC020)资助

Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films

JIAO Ti-Feng^1,2, LIU Ming-Hua²

1. Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China;
2. CAS Key Laboratory of Colloid and Interface Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2012-03-09 Revised:2012-03-28 Published:2012-05-17
Contact: JIAO Ti-Feng, LIU Ming-Hua E-mail:tfjiao@ysu.edu.cn; liumh@iccas.ac.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20903078), China Postdoctoral Science Foundation (2011M500540), Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province, China (2011052), and Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province, China (CPRC020).

摘要/Abstract

摘要： 研究了芳香席夫碱的设计合成、界面相行为以及与铜离子的配位过程, 并与离位合成的铜复合物的界面组装行为进行了对比. 利用表面压-面积等温线、紫外光谱、红外光谱、原子力显微镜等一系列实验方法来详细表征组装膜. 结果表明, 席夫碱配体与铜复合物均可在气液界面上形成稳定的有序组装膜, 并可以转移到固体基片上构筑多层膜. 进而, 席夫碱配体在纯水界面上表现出奇特的相变. 在相变点前后, 二维的平膜变化成了三维的纤维状组装结构. 然而, 对于铜离子亚相上的组装过程却没有出现较大的变化. 两者之间明显的差异可归因于在气液界面超分子组装过程中的分子构型以及疏水性能的不同引起的. 目前的工作为制备和调控有序组装膜提供了有益探索.

关键词: 有序分子膜, 气液界面, 席夫碱, 相变, 组装

Abstract: A novel aromatic Schiff base ligand has been designed and its interfacial phase behavior as well as its in situ coordination with Cu(II) ions on the surface of pure water was compared with those of the corresponding pre-synthesized Cu(II) complex. Surface pressure-area isotherms, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, and atomic force microscopy were used to characterize deposited monolayer and multilayer films of the complexes. Both the ligand and corresponding complex formed stable monolayer or multilayer films at the air/water interface, which could be subsequently transferred onto solid substrates to construct Langmuir-Blodgett films. A novel phase transition was observed when the ligand was spread on the surface of pure water. During this phase transition, the two-dimensional (2D) flat film changed into three-dimensional (3D) fiber-like nanoarchitectures. However, upon coordination with Cu(II) ions, only flat films were obtained. This phenomenon was thought to be caused by the change of molecular conformation and/or hydrophobicity during supramolecular assembly at the air/water interface. This work provides a simple clue for regulating the nanostructures in organized films.

Key words: Organized molecular film, Air/liquid interface, Schiff base, Phase transition, Assembly

MSC2000:

O647

焦体峰, 刘鸣华. 芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变[J]. 物理化学学报, 2012, 28(06): 1418-1424.

JIAO Ti-Feng, LIU Ming-Hua. Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films[J]. Acta Phys. -Chim. Sin., 2012, 28(06): 1418-1424.

参考文献

(1) Ghosh, A.; Mahato, P.; Choudhury, S.; Das, A. Thin Solid Films 2011, 519, 8066.  doi: 10.1016/j.tsf.2011.02.082
(2) Giancane, G.; Filippo, E.; Manno, D.; Serra, A.; Valli, L. J. Colloid Interface Sci. 2011, 363, 199.  doi: 10.1016/j.jcis.2011.06.054
(3) Arya, S. K.; Solanki, P. R.; Datta, M.; Malhotra, B. D. Biosens. Bioelectron. 2009, 24, 2810.  doi: 10.1016/j.bios.2009.02.008
(4) Ariga, K.; Lvov, Y. M.; Kawakami, K.; Ji, Q.; Hill, J. P. Adv. Drug Deliv. Rev. 2011, 63, 762.  doi: 10.1016/j.addr.2011.03.016
(5) Mohnani, S.; Bonifazi, D. Coordin. Chem. Rev. 2010, 254, 2342.  doi: 10.1016/j.ccr.2010.05.006
(6) Zhang, H.; Xin, F.; An, W.; Hao, A.; Wang, X.; Zhao, X.; Liu, Z.; Sun, L. Colloids Surf. A: Physicochem. Eng. Aspects 2010, 363, 78.  doi: 10.1016/j.colsurfa.2010.04.017
(7) Yin, S.; Sun, H.; Yan, Y.; Zhang, H.; Li, W.; Wu, L. J. Colloid Interface Sci. 2011, 361, 548.  doi: 10.1016/j.jcis.2011.06.006
(8) Zhavnerko, G.; Marletta, G. Mater. Sci. Eng. B 2010, 169, 43.  doi: 10.1016/j.mseb.2009.12.005
(9) Pavinatto, F. J.; Gameiro Jr., A. F.; Hidalgo, A. A.; Dinelli, L. R.; Romualdo, L. L.; Batista, A. A.; Barbosa Neto, N. M.; Ferreira, M.; Oliveira Jr., O. N. Appl. Surf. Sci. 2008, 254, 5946.  doi: 10.1016/j.apsusc.2008.03.162
(10) Jin, Y.; Chen, S.; Xin, R.; Zhou, Y. Colloids Surf. B: Biointerf. 2008, 64, 229.  doi: 10.1016/j.colsurfb.2008.01.023
(11) Liu, Y. L.; Wang, W. J.; Gao, X. X.; Xu J. H. Acta Phys. -Chim. Sin. 2011, 27 (8), 1985. [刘云龙, 王文军, 高学喜, 徐建华. 物理化学学报, 2011, 27 (8), 1985.]
(12) Deng, S. P.; Ouyang, J. H. Acta Phys. -Chim. Sin. 2007, 23 (5), 713. [邓穗平, 欧阳健明. 物理化学学报, 2007, 23 (5), 713.]
(13) Xu, B.; Wang, Y.; Zhang, Y. F. J. Chem. Eng. Chin. Univ. 2008, 29 (7), 1317. [徐斌, 王英, 张亚非. 高等学校化学学报, 2008, 29 (7), 1317.]
(14) Gleiche, M.; Chi, L. F.; Fuchs, H. Nature 2000, 403, 173.  doi: 10.1038/35003149
(15) Chen, X.; Hirtz, M.; Fuchs, H.; Chi, L. Langmuir 2007, 23, 2280.  doi: 10.1021/la062938x
(16) Pignataro, B.; Sardone, L.; Marletta, G. Langmuir 2003, 19, 5912.  doi: 10.1021/la034557e
(17) Moraille, P.; Badia, A. Langmuir 2003, 19, 8041.  doi: 10.1021/la034727n
(18) Gong, A.; Liu, Y.; Liu, M.; Xi, F. Thin Solid Films 2002, 406, 228.  doi: 10.1016/S0040-6090(01)01786-2
(19) Jiao, T.; Zhou, J.; Liu, M.; Wang, S.; Zhou, J. X.; Zhang, F. J. Dispersion Sci. Technol. 2010, 31, 1120.  doi: 10.1080/01932690903224789
(20) Rousso, L.; Friedman, N.; Sheves, M.; Ottolenghi, M. Biochemistry 1995, 34, 12059.  doi: 10.1021/bi00037a049
(21) Das, K.; Sarkar, N.; Ghosh, A. K.; Majumdar, D.; Nath, D. N.; Bhattacharya, K. J. Phys. Chem. 1994, 98, 9126.  doi: 10.1021/j100088a006
(22) Fores, M.; Duran, M.; Sola, M. J. Phys. Chem. A 1999, 103, 4525.  doi: 10.1021/jp984773+
(23) Acuna, A. U.; Amat Guerri, F.; Costela, A.; Douhal, A.; Figuera, J. M.; Florido, F.; Sastre, R. Chem. Phys. Lett. 1991, 187, 98.  doi: 10.1016/0009-2614(91)90491-Q
(24) Jiao, T.; Zhou, J.; Zhou, J. X.; Gao, L.; Xing, Y.; Li, X. Iran. Polym. J. 2011, 20, 123.
(25) Sundari, S. S.; Dhathathreyan, A.; Kanthimathi, M.; Nair, B. U. Langmuir 1997, 13, 4923.  doi: 10.1021/la970125q
(26) Vijayalakshmi, R.; Dhathathreyan, A.; Kanthimathi, M.; Subramanian, V.; Nair, B. U.; Ramasami, T. Langmuir 1999, 15, 2898.  doi: 10.1021/la9807356
(27) Nagel, J.; Oertel, U.; Friedel, P.; Komber, H.; Mobius, D. Langmuir 1997, 13, 4693.  doi: 10.1021/la9621269
(28) Liang, Y. Q.; Zhang, Z.; Wu, L.; Tian, Y.; Chen, H. J. Colloid Interface Sci. 1996, 178, 714.  doi: 10.1006/jcis.1996.0169
(29) Liang, Y. Q.; Wu, L.; Tian, Y.; Zhang, Z.; Chen, H. J. Colloid Interface Sci. 1996, 178, 703.  doi: 10.1006/jcis.1996.0168
(30) Yin, M.; Jiao, T.; Liu, M. Chin. Chem. Lett. 2007, 18, 30.  doi: 10.1016/j.cclet.2006.11.008
(31) Jiao, T.; Liu, M. J. Phys. Chem. B 2005, 109, 2532.  doi: 10.1021/jp045258g
(32) Jiao, T.; Liu, M. J. Colloid Interface Sci. 2006, 299, 815.  doi: 10.1016/j.jcis.2006.02.037
(33) Jiao, T.; Liu, M. Langmuir 2006, 22, 5005.  doi: 10.1021/la060343w
(34) Jiao, T.; Zhang, G.; Liu, M. J. Phys. Chem. B 2007, 111, 3090.  doi: 10.1021/jp067287s
(35) Toksoz, S.; Mammadov, R.; Tekinay, A. B.; Guler, M. O. J. Colloid Interface Sci. 2011, 356, 131.  doi: 10.1016/j.jcis.2010.12.076
(36) Al-Saleh, M. H.; Sundararaj, U. Carbon 2009, 47, 2.  doi: 10.1016/j.carbon.2008.09.039
(37) Lu, X. J.; Dou, H.; Yang, S. D.; Hao, L.; Zhang, F.; Zhang, X. G. Acta Phys. -Chim. Sin. 2011, 27 (10), 2333. [卢向军, 窦辉, 杨苏东, 郝亮, 张方, 张校刚. 物理化学学报, 2011, 27 (10), 2333.]
(38) Li, Y. J.; Cao, T. P.; Wang, C. H.; Shao, C. L. J. Chem. Eng. Chin. Univ. 2011, 32 (11), 2490. [李跃军, 曹铁平, 王长华, 邵长路. 高等学校化学学报, 2011, 32 (11), 2490.]

[1]	李凯旋, 张泰隆, 李会增, 李明珠, 宋延林. 纳米粒子的精准组装[J]. 物理化学学报, 2020, 36(9): 1911057 -0 .
[2]	张静, 王丽娜, 陈晓飞, 王玉峰, 牛成艳, 吴立新, 唐智勇. 氧化还原对Lindqvist型多金属氧簇复合物自组装的动态调控[J]. 物理化学学报, 2020, 36(9): 1912002 -0 .
[3]	赵亚楠, 何敏, 刘晓芳, 刘斌, 杨建辉. 金二元纳米晶超晶格的自组装和结构表征[J]. 物理化学学报, 2020, 36(9): 1908041 -0 .
[4]	邓静,马涛,常自伟,赵伟静,杨俊. 基于固体核磁共振方法的蛋白质组装体三维结构解析[J]. 物理化学学报, 2020, 36(4): 1905019 -0 .
[5]	陈锐杰,李娣,方振远,黄元勇,罗必富,施伟东. In₂O₃三维纳米结构的控制合成及高效光解水产氢活性研究[J]. 物理化学学报, 2020, 36(3): 1903047 -0 .
[6]	高飞雪, 陈拥军, 刘冬生, 刘鸣华, 田中群, 张希. “可控自组装体系及其功能化”重大研究计划取得系列重要研究成果[J]. 物理化学学报, 2020, 36(11): 2006060 -0 .
[7]	肖军燕, 齐利民. 环糊精与表面活性剂主客体作用诱导的金纳米棒可控自组装[J]. 物理化学学报, 2020, 36(10): 1910001 -0 .
[8]	邢蕊蕊, 邹千里, 闫学海. 肽基超分子胶体[J]. 物理化学学报, 2020, 36(10): 1909048 -0 .
[9]	方佳丽, 陈新, 李唱, 吴玉莲. 原位液体室透射电镜观察金纳米棒/石墨烯复合物的形成和运动过程[J]. 物理化学学报, 2019, 35(8): 808 -815 .
[10]	焦建梅,徐桂英,辛霞. 胆酸盐参与的自组装及微纳米材料制备[J]. 物理化学学报, 2019, 35(7): 684 -696 .
[11]	冯英杰, 王进平, 刘丽丽, 王习东. ZnO纳米棒阵列到纳米管结构的自转化机制及其在相变封装材料中的应用[J]. 物理化学学报, 2019, 35(6): 644 -650 .
[12]	赵喆, 卢岳, 张振华, 隋曼龄. 原位透射电子显微镜观察电荷驱动的氧化物纳米颗粒水中自组装[J]. 物理化学学报, 2019, 35(5): 539 -545 .
[13]	刘恒昌,冯玉军. CO₂诱导的五嵌段非离子共聚物与阴离子氟碳表面活性剂的相互作用[J]. 物理化学学报, 2019, 35(4): 408 -414 .
[14]	程晓蒙,焦东霞,梁志豪,魏金金,李宏平,杨俊佼. 聚苯乙烯-聚4-乙烯基吡啶两亲嵌段共聚物在CO₂膨胀液体中的组装行为[J]. 物理化学学报, 2018, 34(8): 945 -951 .
[15]	蒋东梅,薄乐,朱挺,陶俊彬,杨小平. 锌-稀土矩形纳米簇的构筑及近红外发光性能[J]. 物理化学学报, 2018, 34(7): 812 -817 .

芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变

Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0