芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变

doi:10.3866/PKU.WHXB201203291

物理化学学报 >> 2012, Vol. 28 >> Issue (06): 1418-1424.doi: 10.3866/PKU.WHXB201203291

芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变

焦体峰^1,2, 刘鸣华²

1. 燕山大学环境与化学工程学院, 河北省应用化学重点实验室, 河北秦皇岛 066004;
2. 中国科学院化学研究所, 胶体、界面与化学热力学院重点实验室, 北京 100190

收稿日期:2012-03-09 修回日期:2012-03-28 发布日期:2012-05-17
通讯作者: 焦体峰, 刘鸣华 E-mail:tfjiao@ysu.edu.cn; liumh@iccas.ac.cn
基金资助:
国家自然科学基金(20903078), 中国博士后科学基金(2011M500540), 河北省留学回国人员科技择优资助经费(2011052)和河北省高校百名优秀创新人才支持计划(CPRC020)资助

Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films

JIAO Ti-Feng^1,2, LIU Ming-Hua²

1. Hebei Key Laboratory of Applied Chemistry, School of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao 066004, Hebei Province, P. R. China;
2. CAS Key Laboratory of Colloid and Interface Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

Received:2012-03-09 Revised:2012-03-28 Published:2012-05-17
Contact: JIAO Ti-Feng, LIU Ming-Hua E-mail:tfjiao@ysu.edu.cn; liumh@iccas.ac.cn
Supported by:
The project was supported by the National Natural Science Foundation of China (20903078), China Postdoctoral Science Foundation (2011M500540), Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province, China (2011052), and Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province, China (CPRC020).

摘要/Abstract

摘要： 研究了芳香席夫碱的设计合成、界面相行为以及与铜离子的配位过程, 并与离位合成的铜复合物的界面组装行为进行了对比. 利用表面压-面积等温线、紫外光谱、红外光谱、原子力显微镜等一系列实验方法来详细表征组装膜. 结果表明, 席夫碱配体与铜复合物均可在气液界面上形成稳定的有序组装膜, 并可以转移到固体基片上构筑多层膜. 进而, 席夫碱配体在纯水界面上表现出奇特的相变. 在相变点前后, 二维的平膜变化成了三维的纤维状组装结构. 然而, 对于铜离子亚相上的组装过程却没有出现较大的变化. 两者之间明显的差异可归因于在气液界面超分子组装过程中的分子构型以及疏水性能的不同引起的. 目前的工作为制备和调控有序组装膜提供了有益探索.

关键词: 有序分子膜, 气液界面, 席夫碱, 相变, 组装

Abstract: A novel aromatic Schiff base ligand has been designed and its interfacial phase behavior as well as its in situ coordination with Cu(II) ions on the surface of pure water was compared with those of the corresponding pre-synthesized Cu(II) complex. Surface pressure-area isotherms, ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, and atomic force microscopy were used to characterize deposited monolayer and multilayer films of the complexes. Both the ligand and corresponding complex formed stable monolayer or multilayer films at the air/water interface, which could be subsequently transferred onto solid substrates to construct Langmuir-Blodgett films. A novel phase transition was observed when the ligand was spread on the surface of pure water. During this phase transition, the two-dimensional (2D) flat film changed into three-dimensional (3D) fiber-like nanoarchitectures. However, upon coordination with Cu(II) ions, only flat films were obtained. This phenomenon was thought to be caused by the change of molecular conformation and/or hydrophobicity during supramolecular assembly at the air/water interface. This work provides a simple clue for regulating the nanostructures in organized films.

Key words: Organized molecular film, Air/liquid interface, Schiff base, Phase transition, Assembly

MSC2000:

O647

焦体峰, 刘鸣华. 芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变[J]. 物理化学学报, 2012, 28(06): 1418-1424.

JIAO Ti-Feng, LIU Ming-Hua. Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films[J]. Acta Phys. -Chim. Sin., 2012, 28(06): 1418-1424.

参考文献

(1) Ghosh, A.; Mahato, P.; Choudhury, S.; Das, A. Thin Solid Films 2011, 519, 8066.  doi: 10.1016/j.tsf.2011.02.082
(2) Giancane, G.; Filippo, E.; Manno, D.; Serra, A.; Valli, L. J. Colloid Interface Sci. 2011, 363, 199.  doi: 10.1016/j.jcis.2011.06.054
(3) Arya, S. K.; Solanki, P. R.; Datta, M.; Malhotra, B. D. Biosens. Bioelectron. 2009, 24, 2810.  doi: 10.1016/j.bios.2009.02.008
(4) Ariga, K.; Lvov, Y. M.; Kawakami, K.; Ji, Q.; Hill, J. P. Adv. Drug Deliv. Rev. 2011, 63, 762.  doi: 10.1016/j.addr.2011.03.016
(5) Mohnani, S.; Bonifazi, D. Coordin. Chem. Rev. 2010, 254, 2342.  doi: 10.1016/j.ccr.2010.05.006
(6) Zhang, H.; Xin, F.; An, W.; Hao, A.; Wang, X.; Zhao, X.; Liu, Z.; Sun, L. Colloids Surf. A: Physicochem. Eng. Aspects 2010, 363, 78.  doi: 10.1016/j.colsurfa.2010.04.017
(7) Yin, S.; Sun, H.; Yan, Y.; Zhang, H.; Li, W.; Wu, L. J. Colloid Interface Sci. 2011, 361, 548.  doi: 10.1016/j.jcis.2011.06.006
(8) Zhavnerko, G.; Marletta, G. Mater. Sci. Eng. B 2010, 169, 43.  doi: 10.1016/j.mseb.2009.12.005
(9) Pavinatto, F. J.; Gameiro Jr., A. F.; Hidalgo, A. A.; Dinelli, L. R.; Romualdo, L. L.; Batista, A. A.; Barbosa Neto, N. M.; Ferreira, M.; Oliveira Jr., O. N. Appl. Surf. Sci. 2008, 254, 5946.  doi: 10.1016/j.apsusc.2008.03.162
(10) Jin, Y.; Chen, S.; Xin, R.; Zhou, Y. Colloids Surf. B: Biointerf. 2008, 64, 229.  doi: 10.1016/j.colsurfb.2008.01.023
(11) Liu, Y. L.; Wang, W. J.; Gao, X. X.; Xu J. H. Acta Phys. -Chim. Sin. 2011, 27 (8), 1985. [刘云龙, 王文军, 高学喜, 徐建华. 物理化学学报, 2011, 27 (8), 1985.]
(12) Deng, S. P.; Ouyang, J. H. Acta Phys. -Chim. Sin. 2007, 23 (5), 713. [邓穗平, 欧阳健明. 物理化学学报, 2007, 23 (5), 713.]
(13) Xu, B.; Wang, Y.; Zhang, Y. F. J. Chem. Eng. Chin. Univ. 2008, 29 (7), 1317. [徐斌, 王英, 张亚非. 高等学校化学学报, 2008, 29 (7), 1317.]
(14) Gleiche, M.; Chi, L. F.; Fuchs, H. Nature 2000, 403, 173.  doi: 10.1038/35003149
(15) Chen, X.; Hirtz, M.; Fuchs, H.; Chi, L. Langmuir 2007, 23, 2280.  doi: 10.1021/la062938x
(16) Pignataro, B.; Sardone, L.; Marletta, G. Langmuir 2003, 19, 5912.  doi: 10.1021/la034557e
(17) Moraille, P.; Badia, A. Langmuir 2003, 19, 8041.  doi: 10.1021/la034727n
(18) Gong, A.; Liu, Y.; Liu, M.; Xi, F. Thin Solid Films 2002, 406, 228.  doi: 10.1016/S0040-6090(01)01786-2
(19) Jiao, T.; Zhou, J.; Liu, M.; Wang, S.; Zhou, J. X.; Zhang, F. J. Dispersion Sci. Technol. 2010, 31, 1120.  doi: 10.1080/01932690903224789
(20) Rousso, L.; Friedman, N.; Sheves, M.; Ottolenghi, M. Biochemistry 1995, 34, 12059.  doi: 10.1021/bi00037a049
(21) Das, K.; Sarkar, N.; Ghosh, A. K.; Majumdar, D.; Nath, D. N.; Bhattacharya, K. J. Phys. Chem. 1994, 98, 9126.  doi: 10.1021/j100088a006
(22) Fores, M.; Duran, M.; Sola, M. J. Phys. Chem. A 1999, 103, 4525.  doi: 10.1021/jp984773+
(23) Acuna, A. U.; Amat Guerri, F.; Costela, A.; Douhal, A.; Figuera, J. M.; Florido, F.; Sastre, R. Chem. Phys. Lett. 1991, 187, 98.  doi: 10.1016/0009-2614(91)90491-Q
(24) Jiao, T.; Zhou, J.; Zhou, J. X.; Gao, L.; Xing, Y.; Li, X. Iran. Polym. J. 2011, 20, 123.
(25) Sundari, S. S.; Dhathathreyan, A.; Kanthimathi, M.; Nair, B. U. Langmuir 1997, 13, 4923.  doi: 10.1021/la970125q
(26) Vijayalakshmi, R.; Dhathathreyan, A.; Kanthimathi, M.; Subramanian, V.; Nair, B. U.; Ramasami, T. Langmuir 1999, 15, 2898.  doi: 10.1021/la9807356
(27) Nagel, J.; Oertel, U.; Friedel, P.; Komber, H.; Mobius, D. Langmuir 1997, 13, 4693.  doi: 10.1021/la9621269
(28) Liang, Y. Q.; Zhang, Z.; Wu, L.; Tian, Y.; Chen, H. J. Colloid Interface Sci. 1996, 178, 714.  doi: 10.1006/jcis.1996.0169
(29) Liang, Y. Q.; Wu, L.; Tian, Y.; Zhang, Z.; Chen, H. J. Colloid Interface Sci. 1996, 178, 703.  doi: 10.1006/jcis.1996.0168
(30) Yin, M.; Jiao, T.; Liu, M. Chin. Chem. Lett. 2007, 18, 30.  doi: 10.1016/j.cclet.2006.11.008
(31) Jiao, T.; Liu, M. J. Phys. Chem. B 2005, 109, 2532.  doi: 10.1021/jp045258g
(32) Jiao, T.; Liu, M. J. Colloid Interface Sci. 2006, 299, 815.  doi: 10.1016/j.jcis.2006.02.037
(33) Jiao, T.; Liu, M. Langmuir 2006, 22, 5005.  doi: 10.1021/la060343w
(34) Jiao, T.; Zhang, G.; Liu, M. J. Phys. Chem. B 2007, 111, 3090.  doi: 10.1021/jp067287s
(35) Toksoz, S.; Mammadov, R.; Tekinay, A. B.; Guler, M. O. J. Colloid Interface Sci. 2011, 356, 131.  doi: 10.1016/j.jcis.2010.12.076
(36) Al-Saleh, M. H.; Sundararaj, U. Carbon 2009, 47, 2.  doi: 10.1016/j.carbon.2008.09.039
(37) Lu, X. J.; Dou, H.; Yang, S. D.; Hao, L.; Zhang, F.; Zhang, X. G. Acta Phys. -Chim. Sin. 2011, 27 (10), 2333. [卢向军, 窦辉, 杨苏东, 郝亮, 张方, 张校刚. 物理化学学报, 2011, 27 (10), 2333.]
(38) Li, Y. J.; Cao, T. P.; Wang, C. H.; Shao, C. L. J. Chem. Eng. Chin. Univ. 2011, 32 (11), 2490. [李跃军, 曹铁平, 王长华, 邵长路. 高等学校化学学报, 2011, 32 (11), 2490.]

[1]	方佳丽, 陈新, 李唱, 吴玉莲. 原位液体室透射电镜观察金纳米棒/石墨烯复合物的形成和运动过程[J]. 物理化学学报, 2019, 35(8): 808 -815 .
[2]	焦建梅,徐桂英,辛霞. 胆酸盐参与的自组装及微纳米材料制备[J]. 物理化学学报, 2019, 35(7): 684 -696 .
[3]	冯英杰, 王进平, 刘丽丽, 王习东. ZnO纳米棒阵列到纳米管结构的自转化机制及其在相变封装材料中的应用[J]. 物理化学学报, 2019, 35(6): 644 -650 .
[4]	赵喆, 卢岳, 张振华, 隋曼龄. 原位透射电子显微镜观察电荷驱动的氧化物纳米颗粒水中自组装[J]. 物理化学学报, 2019, 35(5): 539 -545 .
[5]	刘恒昌,冯玉军. CO₂诱导的五嵌段非离子共聚物与阴离子氟碳表面活性剂的相互作用[J]. 物理化学学报, 2019, 35(4): 408 -414 .
[6]	程晓蒙,焦东霞,梁志豪,魏金金,李宏平,杨俊佼. 聚苯乙烯-聚4-乙烯基吡啶两亲嵌段共聚物在CO₂膨胀液体中的组装行为[J]. 物理化学学报, 2018, 34(8): 945 -951 .
[7]	蒋东梅,薄乐,朱挺,陶俊彬,杨小平. 锌-稀土矩形纳米簇的构筑及近红外发光性能[J]. 物理化学学报, 2018, 34(7): 812 -817 .
[8]	黄丽丽,邵翔. CO与蜜勒胺自组装膜协同作用制备Au单原子及多原子物种[J]. 物理化学学报, 2018, 34(12): 1390 -1396 .
[9]	王琳,肖立志,郭龙,廖广志,张岩,戈革. 纳米自组装γ-Al₂O₃孔隙结构的核磁共振表征[J]. 物理化学学报, 2017, 33(8): 1589 -1598 .
[10]	张洪芝,张志庆,王芳,周亭,王秀凤,张国栋,刘婷婷,刘淑贞. 结构DNA纳米技术应用新进展[J]. 物理化学学报, 2017, 33(8): 1520 -1532 .
[11]	鞠广凯,陶占良,陈军. α-MnO₂纳米管自组装微球的可控制备及电化学性能[J]. 物理化学学报, 2017, 33(7): 1421 -1428 .
[12]	陈爱喜,汪宏,段赛,张海明,徐昕,迟力峰. 电势诱导的N-异丁酰基-L-半胱氨酸分子在金(111)表面的相转变[J]. 物理化学学报, 2017, 33(5): 1010 -1016 .
[13]	SCHLERETH Andrew,NOOMUNA Panae,GAO Pei. 应用纳米球刻蚀法在自组装膜修饰的硅表面生成中尺度的网状蛋白层[J]. 物理化学学报, 2017, 33(4): 810 -815 .
[14]	曾梦琪,张涛,谭丽芳,付磊. 液态金属催化剂:二维材料的点金石[J]. 物理化学学报, 2017, 33(3): 464 -475 .
[15]	张珍,谢文俊,杨奕,孙耿,高毅勤. 基于卤键的谢尔宾斯基三角分形自组装的模拟研究[J]. 物理化学学报, 2017, 33(3): 539 -547 .

芳香席夫碱衍生物在有序分子膜中的相行为与二维-三维形变

Phase Behaviors and 2D-3D Morphological Transition of Aromatic Schiff Base Derivatives in Organized Molecular Films

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 10