阳极氧化物纳米孔道和TiO2纳米管形成机理的研究进展

doi:10.3866/PKU.WHXB201204093

摘要/Abstract

摘要： 自组织有序的TiO₂纳米管和多孔型阳极氧化膜(PAO)因其潜在的应用价值而倍受关注. 阀金属的阳极氧化研究了80 多年, 但是六棱柱元胞结构和多孔纳米管的形成机理至今尚不清楚. 本文不是简单地综述PAO的形成机理, 而是从更宽的视角综述了致密型阳极氧化膜与PAO的本质联系和形貌差异. 对比两种膜的形貌差异和生长过程有助于孔洞形成本质的认识. 简要综述了PAO的传统“场致助溶(FAD)”理论和局限性, 重点综述了PAO形成机理的最新研究进展, 包括粘性流动模型、阻挡层击穿模型、氧气气泡成孔模型、等电场强度模型等. 在充分对比分析最新成果的基础上, 对PAO机理研究的发展趋势进行了展望: 采用超声氧化、真空或高压条件下氧化以及对电解液中添加碳酸钠或还原剂等方法, 对揭示孔洞形成和自组织的本质将会有很大帮助;从电流和阳极氧化效率角度入手, 是探究传统FAD理论的物理本质的有效途径.

关键词: 致密型阳极氧化物, 多孔型阳极氧化物, 形成机理, 阳极氧化, 自组织

Abstract: Self-ordered porous anodic TiO₂ nanotubes and other porous anodic oxides (PAO) have received considerable attention because of their potential for high technological application in a number of fields. The anodization of valve metals has been widely investigated over the last eight decades. The formation mechanisms of hexagonal cells and nanotubes, however, have remained unclear until now. Simply reviewing the mechanisms of PAO formation was not the aim of this research and we were more interested in reviewing the forming processes of compact anodic oxides (CAO) and investigating the relationship between the PAO and CAO, to better understand the pore generating mechanisms. The present work introduces the differences between PAO and CAO films, as well as reviewing the traditional theories of PAO films and their deficiencies. Recent progress in the formation mechanism of PAO, including the viscous flow, breakdown, equifield strength, and oxygen bubbles models has been reviewed in detail. The perspective on future developments for the PAO forming mechanism has been tentatively discussed. Based on sufficient analysis of the latest findings, it has been proposed that several approaches may be employed for investigating the pore forming and self-ordering mechanisms. These new approaches include ultrasound-assisted anodizing, anodizing under vacuum or high pressure and adding sodium carbonate or a reducing agent to the PAO-forming electrolytes. An investigation of changes in the current and anodizing efficiencies would also be an effective approach for better understanding the physical nature of fieldassisted dissolution (FAD).

Key words: Compact anodic oxide, Porous anodic oxide, Formation mechanism, Anodization, Self-ordering

MSC2000:

O646

朱绪飞, 韩华, 宋晔, 段文强. 阳极氧化物纳米孔道和TiO₂纳米管形成机理的研究进展[J]. 物理化学学报, 2012, 28(06): 1291-1305.

ZHU Xu-Fei, HAN Hua, SONG Ye, DUAN Wen-Qiang. Research Progress in Formation Mechanism of TiO₂ Nanotubes and Nanopores in Porous Anodic Oxide[J]. Acta Phys. -Chim. Sin., 2012, 28(06): 1291-1305.

参考文献

(1) Vermilyea, D. A. Acta Metall. 1953, 1, 282.  doi: 10.1016/0001-6160(53)90101-1
(2) Hunter, M. S.; Fowler, P. J. Electrochem. Soc. 1954, 101, 481.  doi: 10.1149/1.2781304
(3) Shankar, K.; Basham, J. I.; Allam, N. K.; Varghese, O. K.; Mor, G. K.; Feng, X. J.; Paulose, M.; Seabold, J. A.; Choi, K. S.; Grimes, C. A. J. Phys. Chem. C 2009, 113, 6327.  doi: 10.1021/jp809385x
(4) Spooner, R. C. Nature 1963, 200, 1002.  doi: 10.1038/2001002a0
(5) Tsuchiya, H.; Macak, J. M.; Sieber, I.; Taveira, L.; Ghicov, A.; Sirotna, K.; Schmuki, P. Electrochem. Commun. 2005, 7, 295.  doi: 10.1016/j.elecom.2005.01.003
(6) Sieber, I.; Hildebrand, H.; Friedrich, A.; Schmuki, P. Electrochem. Commun. 2005, 7, 97.  doi: 10.1016/j.elecom.2004.11.012
(7) Whitney, T. M.; Searson, P. C.; Jiang, J. S.; Chien, C. L. Science 1993, 261, 1316.  doi: 10.1126/science.261.5126.1316
(8) Zhao, L. L.; Steinhart, M.; Gösele, U.; Schlecht, S. Adv. Mater. 2008, 20, 1218.  doi: 10.1002/adma.200702376
(9) Mahima, S.; Kannan, R.; Komath, I.; Aslam, M.; Pillai, V. K. Chem. Mater. 2008, 20, 601.  doi: 10.1021/cm702102b
(10) Evans, P. R.; Zhu, X. H.; Baxter, P.; McMillen, M.; McPhillips, J.; Morrison, F. D.; Scott, J. F.; Pollard, R. J.; Bowman, R. M.; Gregg, J. M. Nano Lett. 2007, 7, 1134.  doi: 10.1021/nl0626028
(11) Huang, C.; Jiang, J.; Lu, M.; Sun, L.; Meletis, E. I.; Hao, Y. Nano Lett. 2009, 9, 4297.  doi: 10.1021/nl902529y
(12) Gu, D.; Baumgart, H.; Abdel-Fattah, T. M.; Namkoong, G. ACS Nano 2010, 4, 753.  doi: 10.1021/nn901250w
(13) Jha, H.; Song, Y. Y.; Yang, M.; Schmuki, P. Electrochem. Commun. 2011, 13, 934.  doi: 10.1016/j.elecom.2011.06.004
(14) Beranek, R.; Hildebrand, H.; Schmuki, P. Electrochem. Solid State Lett. 2003, 6, B12.
(15) Cai, Q. Y.; Paulose, M.; Varghese, O. K.; Grimes, C. A. J. Mater. Res. 2005, 20, 230.  doi: 10.1557/JMR.2005.0020
(16) Albu, S. P.; Kim, D.; Schmuki, P. Angew. Chem. Int. Edit. 2008, 47, 1916.  doi: 10.1002/anie.200704144
(17) Habazaki, H.; Teraoka, M.; Aoki, Y.; Skeldon, P.; Thompson, G. E. Electrochim. Acta 2010, 55, 3939.  doi: 10.1016/j.electacta.2010.02.036
(18) Lee, K.; Kim, D.; Roy, P.; Paramasivam, I.; Birajdar, B. I.; Spiecker, E.; Schmuki, P. J. Am. Chem. Soc. 2010, 132, 1478.  doi: 10.1021/ja910045x
(19) Wei,W.; Macak, J. M.; Schmuki, P. Electrochem. Commun. 2008, 10, 428.  doi: 10.1016/j.elecom.2008.01.004
(20) Tsuchiya, H.; Macak, J. M.; Sieber, I.; Schmuki, P. Small 2005, 1, 722.  doi: 10.1002/smll.200400163
(21) El-Sayed, H.; Singh, S.; Greiner, M. T.; Kruse, P. Nano Lett. 2006, 6, 2995.  doi: 10.1021/nl062347r
(22) Allam, N. K.; Feng, X. J.; Grimes, C. A. Chem. Mater. 2008, 20, 6477.  doi: 10.1021/cm801472y
(23) Tsuchiya, H.; Schmuki, P. Electrochem. Commun. 2004, 6, 1131.  doi: 10.1016/j.elecom.2004.09.003
(24) Yang, S.; Aoki, Y.; Habazaki, H. Appl. Surf. Sci. 2011, 257, 8190.  doi: 10.1016/j.apsusc.2011.01.041
(25) Barbara, P.; Andreas, K.; Thomas, B. Adv. Mater. 2011, 23, 2395.  doi: 10.1002/adma.201002828
(26) Alam, K. M.; Singh, A. P.; Bodepudi, S. C.; Pramanik, S. Surf. Sci. 2011, 605, 441.  doi: 10.1016/j.susc.2010.11.015
(27) Li, M.; Liu, Y.;Wang, H.; Shen, H. Appl. Energ. 2011, 88, 825.  doi: 10.1016/j.apenergy.2010.09.017
(28) Jin, Z.; Meng, F. L.; Liu, J. Y.; Li, M. Q.; Kong, L. T.; Liu, J. H. Sensor. Actuat. B-Chem. 2011, 157, 641.  doi: 10.1016/j.snb.2011.05.044
(29) Wang, D. A.; Liu, Y.;Wang, C.W.; Zhou, F. Prog. Chem. 2010, 22, 1035. [王道爱, 刘盈, 王成伟, 周峰. 化学进展, 2010, 22, 1035.]
(30) Li, H. H.; Chen, R. F.; Ma, C.; Zhang, S. L.; An, Z. F.; Huang, W. Acta Phys. -Chim. Sin. 2011, 27, 1017. [李欢欢, 陈润锋, 马琮, 张胜兰, 安众福, 黄维. 物理化学学报, 2011, 27, 1017.]  doi: 10.3866/PKU.WHXB20110514
(31) Ye, Q. M.; Song, Y.; Liu, P.; Hu, J. J. Prog. Chem. 2011, 23, 2617. [叶秋梅, 宋晔, 刘鹏, 胡隽隽. 化学进展, 2011, 23, 2617.]
(32) Zheng, Q.; Zhou, B. X.; Bai, J.; Cai,W. M.; Liao, J. S. Prog. Chem. 2007, 19, 117. [郑青, 周保学, 白晶, 蔡为民, 廖俊生, 化学进展, 2007, 19, 117.]
(33) Diggle, J.W.; Downie, T. C.; Goulding, C.W. Chem. Rev. 1969, 69, 365.  10.1021/cr60259a005
(34) Despic, A.; Parkhutik, V. P. Modern Aspects of Electrochemistry; Plenum Press: New York, 1989; Vol. 23, pp 401-458.
(35) Parkhutik, V. P.; Shershulsky, V. I. J. Phys. D: Appl. Phys. 1992, 25, 1258.  doi: 10.1088/0022-3727/25/8/017
(36) Thompson, G. E. Thin Solid Films 1997, 297, 192.  doi: 10.1016/S0040-6090(96)09440-0
(37) Dickey, J. R.; Davidson, J. L.; Tzeng, Y. J. Electrochem. Soc. 1989, 136, 1772.  doi: 10.1149/1.2097010
(38) Song, Y.; Zhu, X. F.;Wang, X. L.; Che, J. F.; Du, Y. J. Appl. Electrochem. 2001, 31, 1273.  doi: 10.1023/A:1012746926209
(39) Seruga, M.; Hasenay, D. J. Appl. Electrochem. 2001, 31, 961.  doi: 10.1023/A:1017556323508
(40) Zhu, Q.; Song, Y.; Zhu, X. F.;Wang, X. L. J. Electroanal. Chem. 2007, 601, 229.  doi: 10.1016/j.jelechem.2006.11.016
(41) Simon, P.; Gogotsi, Y. Nat. Mater. 2008, 7, 845.  doi: 10.1038/nmat2297
(42) Song, Y.; Zhu, X. F.;Wang, X.;Wang, M. J. J. Power Sources 2006, 157, 610.  doi: 10.1016/j.jpowsour.2005.07.085
(43) Overmeere, Q. V.; Proost, J. Electrochim. Acta 2010, 55, 4653.  doi: 10.1016/j.electacta.2010.03.042
(44) Li, Y.; Shimada, H.; Sakairi, M.; Shigyo, K.; Takahashi, H.; Seo, M. J. Electrochem. Soc. 1997, 144, 866.  doi: 10.1149/1.1837501
(45) Zhu, X. F.; Liu, L.; Zhao, B. C. The Chinese Journal of Nonferrous Metals 2003, 13, 1031. [朱绪飞, 刘霖, 赵宝昌. 中国有色金属学报, 2003, 13, 1031.]
(46) Lee,W.; Scholz, R.; Gösele, U. Nano Lett. 2008, 8, 2155.  doi: 10.1021/nl080280x
(47) Keller, F.; Hunter, M. S.; Robinson, D. L. J. Electrochem. Soc. 1953, 100, 411.  doi: 10.1149/1.2781142
(48) Vermilyea, D. A. Acta Metall. 1954, 2, 482.  doi: 10.1016/0001-6160(54)90070-X
(49) Lakhiani, D. M.; Shreir, L. L. Nature 1960, 188, 49.  doi: 10.1038/188049a0
(50) O'Sullivan, J. P.;Wood, G. C. Proc. R. Soc. Lond. A 1970, 317, 511.
(51) Thompson, G. E.; Furneaux, R. C.;Wood, G. C.; Richardson, J. A.; Goode, J. S. Nature 1978, 272, 433.  doi: 10.1038/272433a0
(52) Thompson, G. E.;Wood, G. C. Nature 1981, 290, 230.  doi: 10.1038/290230a0
(53) Shimizu, K.; Thompson, G. R.;Wood, G. C. Thin Solid Films 1981, 81, 39.  doi: 10.1016/0040-6090(81)90502-2
(54) Albella, J. M.; Montero, I.; Martinez-Duart, J. M. Electrochim. Acta 1987, 32, 255.  doi: 10.1016/0013-4686(87)85032-6
(55) Furneaux, R. C.; Rigby,W. R.; Davidson, A. P. Nature 1989, 337, 147.  doi: 10.1038/337147a0
(56) Shimizu, K.; Kobayashi, K.; Thompson, G. E. Philos. Mag. A 1992, 66, 643.  doi: 10.1080/01418619208201581
(57) Masuda, H.; Fukuda, K. Science 1995, 268, 1466.  doi: 10.1126/science.268.5216.1466
(58) Li, F. Y.; Zhang, L.; Metzger, R. M. Chem. Mater. 1998, 10, 2470.  doi: 10.1021/cm980163a
(59) Masuda, H.; Hasegwa, F.; Ono, S. J. Electrochem. Soc. 1997, 144, L127
(60) Ono, S.; Saito, M.; Asoh, H. Electrochim. Acta 2005, 51, 827.  doi: 10.1016/j.electacta.2005.05.058
(61) Jessensky, O.; Müller, F.; Gösele, U. Appl. Phys. Lett. 1998, 72, 1173.  doi: 10.1063/1.121004
(62) Li, A. P.; Müller, F.; Birner, A.; Nielsch, K.; Gösele, U. J. Appl. Phys. 1998, 84, 6023.  doi: 10.1063/1.368911
(63) Nielsch, K.; Choi, J.; Schwirn, K.;Wehrspohn, R. B.; Gösele, U. Nano Lett. 2002, 2, 677.  doi: 10.1021/nl025537k
(64) Guo, D. Z.; Hou, S. M.; Xue, Z. Q. Chin. Phys. Lett. 2002, 19, 385.  doi: 10.1088/0256-307X/19/3/330
(65) Macak, J. M.; Tsuchiya, H.; Ghicov, A.; Yasuda, K.; Hahn, R.; Bauer, S.; Schmuki, P. Curr. Opin. Solid St. M 2007, 11, 3.  doi: 10.1016/j.cossms.2007.08.004
(66) Ghicov, A.; Schmuki, P. Chem. Commun. 2009, 2791.
(67) Jiang, X. X.; Zhao, N. Q. Journal of Functional Materials 2005, 36, 487. [江小雪, 赵乃勤. 功能材料, 2005, 36, 487.]  doi: 10.3321/j.issn:1001-9731.2005.04.002
(68) Lai, Y. K.; Sun, L.; Zuo, J.; Lin, C. J. Acta Phys. -Chim. Sin. 2004, 20, 1063. [赖跃坤, 孙岚, 左娟, 林昌健. 物理化学学报, 2004, 20, 1063.]  10.3866/PKU.WHXB20040901
(69) Siejka, J.; Ortega, C.; An, O. J. Electrochem. Soc. 1977, 124, 883.  10.1149/1.2133446
(70) Lee,W.; Schwirn, K.; Steinhart, M.; Pippel, E.; Scholz, R.; Gösele, U. Nat. Nanotechnol. 2008, 3, 234.  doi: 10.1038/nnano.2008.54
(71) Skeldon, P.; Thompson, G. E.; Garcia-Vergara, S. J.; Iglesias- Rubianes, L.; Blanco-Pinzon, C. E. Electrochem. Solid. St. 2006, 9, B47.
(72) Garcia-Vergara, S. J.; Skeldon, P.; Thompson, G. E.; Habazaki, H. Electrochim. Acta 2006, 52, 681.  doi: 10.1016/j.electacta.2006.05.054
(73) Garcia-Vergara, S. J.; Habazaki, H.; Skeldon, P.; Thompson, G. E. Electrochim. Acta 2010, 55, 3175.  doi: 10.1016/j.electacta.2010.01.038
(74) Houser, J. E.; Hebert, K. R. Nat. Mater. 2009, 8, 415.  doi: 10.1038/nmat2423
(75) Houser, J. E., Hebert, K. R. J. Electrochem. Soc. 2006, 153, B566.
(76) Garcia-Vergara, S. J.; Skeldon, P.; Thompson, G. E.; Habazaki, H. Corrosion Sci. 2007, 49, 3772.  doi: 10.1016/j.corsci.2007.03.036
(77) Li, D. D.; Jiang, C. H.; Jiang, J. H.; Ren, X. Mater. Chem. Phys. 2008, 111, 168.  doi: 10.1016/j.matchemphys.2008.03.044
(78) Matykina, E.; Arrabal, R.; Skeldon, P. Surf. Coat. Tech. 2010, 205, 1668.  doi: 10.1016/j.surfcoat.2010.05.014
(79) Coz, F. L.; Arurault, L.; Datas, L. Mater. Charact. 2010, 61, 283.  doi: 10.1016/j.matchar.2009.12.008
(80) Yang, S.; Aoki, Y.; Skeldon, P.; Thompson, G. E.; Habazaki, H. J. Solid State Electrochem. 2011, 15, 689.  doi: 10.1007/s10008-010-1141-6
(81) Oh, J.; Thompson, C. V. Electrochim. Acta 2011, 56, 4044.  doi: 10.1016/j.electacta.2011.02.002
(82) Li, Y. B.; Zheng, M. J.; Ma, L.; Shen,W. Z. Nanotechnology 2006, 17, 5101.  doi: 10.1088/0957-4484/17/20/010
(83) Huang, Q.; Lye,W. K.; Reed, M. L. Nanotechnology 2007, 18, 405302.  doi: 10.1088/0957-4484/18/40/405302
(84) Yao, Z.W.; Zheng, M. J.; Ma, L.; Shen,W. Z. Nanotechnology 2008, 19, 465705.  doi: 10.1088/0957-4484/19/46/465705
(85) Bai, J.; Zhou, B. X.; Li, L. H.; Liu, Y. B.; Zheng, Q.; Shao, J. H.; Zhu, X. Y.; Cai,W. M.; Liao, J. S.; Zou, L. X. J. Mater. Sci. 2008, 43, 1880.  doi: 10.1007/s10853-007-2418-8
(86) Li, D. D.; Jiang, C. H.; Jiang, J. H.; Lu, J. G. Chem. Mater. 2009, 21, 253.  doi: 10.1021/cm8022242
(87) Li, D. D.; Zhao, L.; Jiang, C. H.; Lu, J. G. Nano Lett. 2010, 10, 2766.  doi: 10.1021/nl1004493
(88) Lin, J.; Chen, J. F.; Chen, X. F. Electrochem. Commun. 2010, 12, 1062.  doi: 10.1016/j.elecom.2010.05.027
(89) Lin, J.; Liu, K.; Chen, X. F. Small 2011, 7, 1784.  doi: 10.1002/smll.201002098
(90) Ding, G. Q.; Shen,W. Z.; Zheng, M. J.; Zhou, Z, B. Nanotechnology 2006, 17, 2590.  doi: 10.1088/0957-4484/17/10/024
(91) Ding, G. Q.; Zheng, M. J.; Cu,W. L.; Shen,W. Z. Nanotechnology 2005, 16, 1285.  doi: 10.1088/0957-4484/16/8/050
(92) Cheng,W.; Xu, J. Y.; Hu, J.; Jin, X. J. Chin. J. Inorg. Chem. 2009, 25, 92. [程伟, 徐金叶, 胡静, 金学军. 无机化学学报, 2009, 25, 92.]
(93) Tao, J.; Tao, H. J.; Bao, Z. G.;Wang, L. Rare Metal Mater. Eng. 2009, 38, 967. [陶杰, 陶海军, 包祖国, 王玲. 稀有金属材料与工程, 2009, 38, 967.]
(94) Zhou, C. F.;Wang, Z. Y. J. Inorg. Mater. 2009, 24, 1125. [周成风, 王志义. 无机材料学报, 2009, 24, 1125.]  doi: 10.3724/SP.J.1077.2009.01125
(95) Li, S. Q.; Yin, J. B.; Zhang, G. M. Sci. China Chem. 2010, 53, 1068. [李仕琦, 尹建波, 张耿民. 中国科学: 化学, 2010, 53, 1068.]  doi: 10.1007/s11426-010-0155-3
(96) Chen, X. Q.; Zhang, X.W.; Lei, L. C. The Chinese Journal of Nonferrous Metals 2010, 20, 1724. [陈秀琴, 张兴旺, 雷乐成. 中国有色金属学报, 2010, 20, 1724.]
(97) Li, H. Y.;Wang, J. S.; Chen, X.; Zhou, M. L.; Sun, G. S.; Huang, K. L.; Guo, Q. N. Chin. J. Inorg. Chem. 2010, 26, 217. [李洪义, 王金淑, 陈欣, 周美玲, 孙果宋, 黄科林, 郭秋宁. 无机化学学报, 2010, 26, 217.]
(98) Chen,W.;Wu, J. S.; Yuan, J. H.; Xia, X. H.; Lin, X. H. J. Electroanal. Chem. 2007, 600, 257.  doi: 10.1016/j.jelechem.2006.10.022
(99) Chen,W.;Wu, J. S.; Xia, X. H. ACS Nano 2008, 2, 959.  doi: 10.1021/nn700389j
(100) Li, Y.; Ling, Z. Y.; Chen, S. S.;Wang, J. C. Nanotechnology 2008, 19, 225604.  doi: 10.1088/0957-4484/19/22/225604
(101) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. J. Mater. Chem. 2011, 21, 9661.  doi: 10.1039/c1jm10781j
(102) Li, Y.; Ling, Z. Y.; Hu, X.; Liu, Y. S.; Chang, Y. Chem. Commun. 2011, 47, 2173.  doi: 10.1039/c0cc04907g
(103) Yu, X. F.; Li, Y. X.; Ge,W. Y.; Yang, Q. B.; Zhu, N. F.; Kalantar-Zadeh, K. Nanotechnology 2006, 17, 808.  doi: 10.1088/0957-4484/17/3/033
(104) Wang, D. A.; Liu, Y.; Yu, B.; Zhou, F.; Liu,W. M. Chem. Mater. 2009, 21, 1198.  doi: 10.1021/cm802384y
(105) Zhang, R.; Jiang, K. M.; Zhu, Y.; Qi, H. Y.; Ding, G. Q. Appl. Surf. Sci. 2011, 258, 586.  doi: 10.1016/j.apsusc.2011.08.041
(106) Wang, Y.;Wu, Y. C.; Qin, Y. Q.; Xu, G. B.; Hu, X. Y.; Cui, J. W.; Zheng, H. M.; Hong, Y.; Zhang, X. Y. J. Alloy. Compd. 2011, 509, L157.
(107) Zhao, J. L.;Wang, X. H.; Chen, R. Z.; Li, L. T. Solid State Commun. 2005, 134, 705.  doi: 10.1016/j.ssc.2005.02.028
(108) Li, S. Q.; Zhang, G. M.; Guo, D. Z.; Yu, L. G.; Zhang,W. J. Phys. Chem. C 2009, 113, 12759.  doi: 10.1021/jp903037f
(109) Wang, N.; Zhang,W. D.; Xu, J. P.; Ma, B.; Zhang, Z. Z.; Jin, Q. Y.; Bunte, B.; Hüpkes, J.; Bochem, H. P. J. Solid State Electrochem. 2010, 14, 1377.  doi: 10.1007/s10008-009-0959-2
(110) Xiao, X. F.; Liu, R. F.; Tian, T. J. Alloy. Compd. 2008, 466, 356.  doi: 10.1016/j.jallcom.2007.11.032
(111) Zhu, Y. Y.; Ding, G. Q.; Ding, J. N.; Yuan, N. Y. Nanoscale Res. Lett. 2010, 5, 725.  doi: 10.1007/s11671-010-9538-9
(112) Elsanousi, A.; Zhang, J.; Fadlalla, H. M.; Zhang, F.;Wang, H.; Ding, X.; Huang, Z. X.; Tang, C. J. Mater. Sci. 2008, 43, 7219.  doi: 10.1007/s10853-008-2947-9
(113) Zhang, F.; Chen, S. G.; Yin, Y. S.; Lin, C.; Xue, C. R. J. Alloy. Compd. 2010, 490, 247.  doi: 10.1016/j.jallcom.2009.09.169
(114) Ren, Y.W.; Zhang, K. S. Mater. Lett. 2009, 63, 1925.  doi: 10.1016/j.matlet.2009.06.006
(115) Zhu, X. F.; Li, D.; Song, Y.; Xiao, Y. Mater. Lett. 2005, 59, 3160.  doi: 10.1016/j.matlet.2005.05.038
(116) Yang, X. L.; Zhu, X. F.; Jia, H.; Han, T. Monatsh. Chem. 2009, 140, 595.  doi: 10.1007/s00706-008-0098-y
(117) Zhu, X. F.; Liu, L.; Song, Y.; Jia, H.; Yu, H.; Xiao, X.; Yang, X. L. Mater. Lett. 2008, 62, 4038.  doi: 10.1016/j.matlet.2008.05.062
(118) Zhu, X. F.; Liu, L.; Song, Y.; Jia, H.; Yu, H.; Xiao, X.; Yang, X. L. Monatsh. Chem. 2008, 139, 999.  doi: 10.1007/s00706-008-0893-5
(119) Zhu, X. F.; Song, Y.; Liu, L.;Wang, C.; Zheng, J.; Jia, H.; Wang, X. Nanotechnology 2009, 20, 475303.  doi: 10.1088/0957-4484/20/47/475303
(120) Poinern, G. E. J.; Ali, N.; Fawcett, D. Materials 2011, 4, 487.  doi: 10.3390/ma4030487
(121) Patermarakis, G. J. Electroanal. Chem. 2009, 635, 39.  doi: 10.1016/j.jelechem.2009.07.024
(122) Crossland, A. C.; Habazaki, H.; Shimizu, K.; Skeldon, P.; Thompson, G. E.;Wood, G. C.; Zhou, X.; Smith, C. J. Corrosion Sci. 1999, 41, 1945.  doi: 10.1016/S0010-938X(99)00035-9
(123) Zhou, X.; Thompson, G. E.; Habazaki, H.; Paez, M. A.; Shimizu, K.; Skeldon, P.;Wood, G. C. J. Electrochem. Soc. 2000, 147, 1747.  doi: 10.1149/1.1393428
(124) Habazaki, H.; Konno, H.; Shimizu, K.; Nagata, S.; Skeldon, P.; Thompson, G. E. Corrosion Sci. 2004, 46, 2041.  doi: 10.1016/j.corsci.2003.10.027
(125) Ono, S.; Ichinose, H.; Masuko, N. J. Electrochem. Soc. 1992, 139, L80.
(126) Su, Z. X.; Zhou,W. Z. Science Foundation in China 2008, 16, 36.
(127) Su, Z. X.; Hähner, G.; Zhou,W. Z. J. Mater. Chem. 2008, 18, 5787.  doi: 10.1039/b812432a
(128) Su, Z. X.; Zhou,W. Z. Adv. Mater. 2008, 20, 3663.  doi: 10.1002/adma.200800845
(129) Su, Z. X.; Bühl, M.; Zhou,W. Z. J. Am. Chem. Soc. 2009, 131, 8697.  doi: 10.1021/ja902267b
(130) Su, Z. X.; Zhou,W. Z. J. Mater. Chem. 2009, 19, 2301.  doi: 10.1039/b820504c
(131) Su, Z. X.; Zhou,W. Z. J. Mater. Chem. 2011, 21, 357.  doi: 10.1039/c0jm02521f
(132) Su, Z. X.; Zhou,W. Z. J. Mater. Chem. 2011, 21, 8955.  doi: 10.1039/c0jm04587j
(133) Schwirn, K.; Lee,W.; Hillebrand, R.; Steinhart, M.; Nielsch, K.; Gösele, U. ACS Nano 2008, 2, 302.  doi: 10.1021/nn7001322
(134) Patermarakis, G.; Moussoutzanis, K. Electrochim. Acta 2009, 54, 2434.  doi: 10.1016/j.electacta.2008.11.064
(135) Panaitescu, E.; Richter, C.; Menon, L. J. Electrochem. Soc. 2008, 155, E7.
(136) Friedman, A. L.; Panaitescu, E.; Richter, C.; Menon, L. J. Nanosci. Nanotechnol. 2008, 8, 5864.  doi: 10.1166/jnn.2008.328
(137) Sieber, I. V.; Schmuki, P. J. Electrochem. Soc. 2005, 152, C639.
(138) Al-Abdullah, Z. T. Y.; Shin, Y.; Kler, R.; Perry, C. C.; Zhou,W. Z.; Chen, Q. Nanotechnology 2010, 21, 505601.  doi: 10.1088/0957-4484/21/50/505601
(139) Matykina, E.; Arrabal, R.; Skeldon, P.; Thompson, G. E.; Habazaki, H. Thin Solid Films 2008, 516, 2296.  doi: 10.1016/j.tsf.2007.08.104
(140) Patermarakis, G.; Moussoutzanis, K. J. Electroanal. Chem. 2011, 659, 176.  doi: 10.1016/j.jelechem.2011.05.023
(141) Ispas, A.; Bund, A.; Vrublevsky, I. J. Solid State Electrochem. 2010, 14, 2121.  doi: 10.1007/s10008-010-1043-7
(142) Chung, C. K.; Zhou, R. X.; Liu, T. Y.; Chang,W. T. Nanotechnology 2009, 20, 055301.  doi: 10.1088/0957-4484/20/5/055301
(143) Berger, S.; Albu, S. P.; Schmidt-Stein, F.; Hildebrand, H.; Schmuki, P.; Hammond, J. S.; Paul, D. F.; Reichlmaier, S. Surf. Sci. 2011, 605, L57.
(144) Dong, H. Q.; Pan, X.; Xie, Q.; Meng, Q. Q.; Gao, J. R.;Wang, J. G. Acta Phys. -Chim. Sin. 2012, 28, 44. [董华青, 潘西, 谢琴, 孟强强, 高建荣, 王建国. 物理化学学报, 2012, 28, 44.]  10.3866/PKU.WHXB20122844

[1]	余翠平,王岩,崔接武,刘家琴,吴玉程. TiO₂纳米管阵列的多重改性及其在超级电容器中应用的最新进展[J]. 物理化学学报, 2017, 33(10): 1944-1959.
[2]	白晶莹,李思振,郑大江,张立功,冯立,崔庆新,王景润,姜文武,林昌健. 黑色微弧氧化膜的制备及其表征[J]. 物理化学学报, 2016, 32(9): 2271-2279.
[3]	杜海英, 王兢, 乔俏, 孙炎辉, 邵强, 李晓干. ZnO/PPy异质纳米复合材料的制备、表征及其气敏特性[J]. 物理化学学报, 2015, 31(4): 800-806.
[4]	易超, 熊信柏, 邹智标, 李俊杰, 黄拓, 李彬, 马俊, 曾燮榕. 阳极氧化/GCD新工艺法制备镍基超级电容器薄膜电极[J]. 物理化学学报, 2015, 31(1): 99-104.
[5]	谢丹华, 赵剑曦, 刘琳, 游毅, 魏西莲. 一个高粘弹的阴离子蠕虫胶束体系[J]. 物理化学学报, 2013, 29(07): 1534-1540.
[6]	朱绪飞, 韩华, 马宏图, 路超, 戚卫星, 徐晨. 还原剂对多孔阳极氧化铝纳米孔道结构的影响[J]. 物理化学学报, 2012, 28(11): 2648-2658.
[7]	翟薇, 王建元. 【撤稿】Au纳米颗粒二维超晶格结构的稳定性[J]. 物理化学学报, 2012, 28(11): 9999-9999.
[8]	张华, 胡耀娟, 吴萍, 张卉, 蔡称心. 大长径比有序多孔阳极氧化铝模板的制备及用于镍纳米线阵列[J]. 物理化学学报, 2012, 28(06): 1545-1550.
[9]	赵学艳, 曹宇容, 曹桂荣, 肖瑞杰. 嵌段共聚物L64在1-丁基-3-甲基咪唑四氟硼酸盐离子液体中形成的层状液晶[J]. 物理化学学报, 2012, 28(06): 1411-1417.
[10]	张庆友, 龙海林, 冯秀林, 索净洁, 张丹丹, 李静亚, 许力壮, 许禄. MOLMAP指数及其在变异性预测中的应用[J]. 物理化学学报, 2012, 28(03): 541-546.
[11]	刘妍, 卫中领, 杨富巍, 张昭. 硼砂-对苯二甲酸电解液中AZ91D镁合金的阳极氧化处理[J]. 物理化学学报, 2011, 27(10): 2385-2392.
[12]	李欢欢, 陈润锋, 马琮, 张胜兰, 安众福, 黄维. 阳极氧化法制备二氧化钛纳米管及其在太阳能电池中的应用[J]. 物理化学学报, 2011, 27(05): 1017-1025.
[13]	贾飞, 王周成. 以硼氢化钠为还原剂化学镀镍的电化学研究[J]. 物理化学学报, 2011, 27(03): 633-640.
[14]	肖立新, 段来强, 柴俊一, 王芸, 陈志坚, 曲波, 龚旗煌. 利用钛保护层在ITO电极上直接制备大面积的超薄氧化铝膜[J]. 物理化学学报, 2011, 27(03): 749-753.
[15]	王丹丽, 阮永丰, 张灵翠, 杨红波. ZnO纳米线阵列的电沉积法制备及表征[J]. 物理化学学报, 2010, 26(12): 3369-3372.

阳极氧化物纳米孔道和TiO₂纳米管形成机理的研究进展

Research Progress in Formation Mechanism of TiO₂ Nanotubes and Nanopores in Porous Anodic Oxide

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 10