集流体对可充镁电池电解液电化学性能的影响

doi:10.3866/PKU.WHXB201208032

摘要/Abstract

摘要：

系统研究了铂、镍、不锈钢(SS)、铜、铝五种金属集流体和碳纤维、石墨箔、碳布三种碳纸集流体对“一代” (Mg(AlCl₂BuEt)₂/THF)、“二代” ((PhMgCl)₂-AlCl₃/THF)可充镁电池电解液阳极氧化分解电位和镁沉积-溶出性能的影响。金属镍、不锈钢、铜、铝作为可充镁电池正极的集流体时, 充电至一定电压时自身均会发生腐蚀。其中, 镍和不锈钢可用作充电电压在2.1V(vs Mg/Mg²⁺)以下正极材料的集流体; 铜可用作充电电压在1.8V(vs Mg/Mg²⁺)以下正极材料的集流体。碳集流体比金属集流体具有更高的稳定性, 其中, 碳布作为集流体, 适用于充电电压在2.25V(vs. Mg)(对“一代”电解液)和2.95V(vs Mg/Mg²⁺)(对“二代”电解液)以下的正极材料。

关键词: 可充镁电池, 集流体, 金属, 碳纸, 电解液

Abstract:

The effects of metal (platinum, nickel, stainless steel (SS), copper and aluminum) and carbon paper (carbon fiber, graphite foil and carbon cloth) current collectors on the anodic stability and magnesium deposition-dissolution of the electrolytes (Mg(AlCl₂BuEt)₂/THF and (PhMgCl)₂-AlCl₃/THF) for rechargeable magnesium batteries were studied by cyclic voltammogram and constant current deposition-dissolution measurements. Nickel, stainless steel, copper and aluminum current collectors occur corrosion upon charging process. Nickel or stainless steel exhibits a higher stability, which can be used as the current collector for the cathode materials with a charging voltage under 2.1V (vs Mg/Mg²⁺). While copper is suitable for the cathode with a charging voltage under 1.8V (vs Mg/Mg²⁺). Furthermore, carbon paper current collectors have a higher anodic stability than metals. Carbon cloth is appropriate for the cathode materials with a charging voltage under 2.25V (vs Mg/Mg²⁺) in Mg(AlCl₂BuEt)₂/THF and 2.95V (vs Mg/Mg²⁺) in (PhMgCl)₂-AlCl₃/THF.

Key words: Rechargeable magnesium battery, Current collector, Metal, Carbon paper, Electrolyte

MSC2000:

O646

陈强, 努丽燕娜, 杨军, 凯丽比努尔·克日木, 王久林. 集流体对可充镁电池电解液电化学性能的影响[J]. 物理化学学报, 2012, 28(11): 2625-2631.

CHEN Qiang, NULI Yanna, YANG Jun, KAILIBINUER Kerimu, WANG Jiulin. Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries[J]. Acta Phys. -Chim. Sin., 2012, 28(11): 2625-2631.

参考文献

(1) Gregory, T. D.; Hoffman, R. J.;Winterton, R. C. J. Electrochem. Soc. 1990, 137, 775. doi: 10.1149/1.2086553
(2) Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.;Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Nature2000, 407, 724. doi: 10.1038/35037553
(3) Yuan, H. T.;Wu, F.;Wu, X. L.; Li, Q. Battery Bimonthly 2002,32, 14. [袁华堂, 吴峰, 武绪丽, 李强. 电池, 2002, 32,14.]
(4) Shen, J.; Peng, B.; Tao, Z. L.; Chen, J. Progess in Chemistry2012, 22, 515. [沈健, 彭博, 陶占良, 陈军. 化学进展,2010, 22, 515.]
(5) Zheng, Y. P.; NuLi, Y. N.; Yang, J.; Chen, Q.;Wang, J. L.Chemical Industry and Engineering Progress 2011, 30 (5),1024. [郑育培, 努丽燕娜, 杨军, 陈强, 王久林.化工进展, 2011, 30 (5), 1024.]
(6) Zhao, Q. S.; Nuli, Y. N.; Guo, Y. S.; Yang, J.;Wang, J. L.Progress in Chemistry 2011, 23, 1598. [赵青松, 努丽燕娜,郭永胜, 杨军, 王久林. 化学进展, 2011, 23, 1598.]
(7) Aurbach, D.; Schechter, A.; Moshkovich, M.; Cohen, Y.;J. Electrochem. Soc. 2001, 148, A1004.
(8) Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; Gottlieb, H.E.; Gofer, Y.; Goldberg, I. J. Electrochem. Soc. 2002, 149, A115.
(9) Gizbar, H.; Vestfrid, Y.; Chusid, O.; Gofer, Y.; Gottlieb, H. E.;Marks, V.; Aurbach, D. Organometallics 2004, 23, 3826. doi: 10.1021/om049949a
(10) Vestfried, Y.; Chusid, O.; Gofer, Y.; Aped, P.; Aurbach, D.Organometallics 2007, 26, 3130. doi: 10.1021/om061076s
(11) Viestfried, Y.; Levi, M. D.; Gofer, Y.; Aurbach, D.J. Electroanal. Chem. 2005, 576, 183. doi: 10.1016/j.jelechem.2004.09.034
(12) Aurbach, D.; Suresh, G. S.; Levi, E.; Mitelman, A.; Mizrahi, O.;Chusid, O.; Brunelli, M. Adv. Mater. 2007, 19, 4260. doi: 10.1002/(ISSN)1521-4095
(13) Mizrahi, O.; Amir, N.; Pollak, E.; Chusid, O.; Marks, V.;Gottlieb, H.; Larush, L.; Zinigrad, E.; Aurbach, D.J. Electrochem. Soc. 2008, 155, A103.
(14) Pour, N.; Gofer, Y.; Major, D. T.; Aurbach, D. J. Am. Chem. Soc.2011, 133, 6270. doi: 10.1021/ja1098512
(15) Arora, P.; White, R. E.; Doyle, M. J. Electrochem. Soc. 1998,145, 3647. doi: 10.1149/1.1838857
(16) Tarascon, J.; Guyomard, D. Solid State Ionics 1994, 69, 293.doi: 10.1016/0167-2738(94)90418-9
(17) Kanamura, K.; Toriyama, S.; Shiraishi, S.; Takehara, Z.J. Electrochem. Soc. 1995, 142, 1383. doi: 10.1149/1.2048586
(18) Dahn, J. R; Fuller, E.W.; Obrovac, M.; Von Sacken, U. Solid State Ionics 1994, 69, 265. doi: 10.1016/0167-2738(94)90415-4
(19) Amatucci, G.; Tarascon, J.; Klein, L. Solid State Ionics 1996,83, 167.
(20) Morita, M.; Shibata, T.; Yoshimoto, N.; Ishikawa, M.Electrochim. Acta 2002, 47, 2787. doi: 10.1016/S0013-4686(02)00164-0
(21) Kanamura, K. J. Power Sources 1999, 81-82, 123.
(22) Peng, C. X. Research on the Compatibility between CurrentCollectors and New Ionic Liquid Electrolytes for LithiumSecondary Batteries. Ph. D. Dissertation, Shanghai JiaotongUniversity, Shanghai, 2008. [彭成信. 锂离子电池集流体与新型离子液体电解液的相容性及界面电化学行为研究[D].上海: 上海交通大学, 2008.]
(23) Ni, J. F.; Zhou, H. H.; Chen, J. T.; Zhang, X.Y. Battery Bimonthly2005, 35, 128. [倪江锋, 周恒辉, 陈继涛, 张新祥. 电池,2005, 35, 128.]
(24) Iwakura, C.; Fukumoto, Y.; Inoue, H.; Ohashi, S.; Kobayashi,S.; Tada, H.; Abe, M. J. Power Sources 1997, 68, 3013.
(25) Dai, Y. H.; Zhou, Y. M.;Wang, Q.; Tang, Y.W.; Lu, T. H.; Shen,T. Chinese Battery Industry 2007, 12, 31. [戴跃华, 周益明,王青, 唐亚文, 陆天虹, 沈涛. 电池工业, 2007, 12, 31.]
(26) Aurbach, D.; Turgeman, R.; Chusid, O.; Gofer, Y. Electrochem. Commun. 2001, 3, 252. doi: 10.1016/S1388-2481(01)00148-5
(27) Liebenow, C.; Yang, Z.; Lobitz, P. Electrochem. Commun. 2000,2, 641. doi: 10.1016/S1388-2481(00)00094-1
(28) Tang, Z, Y.; He, Y. B.; Liu, Y. G.; Liu, Q.; Yang, X. X. Corrosion Science and Protection Technology 2007, 19, 265. [唐致远,贺艳兵, 刘元刚, 刘强, 阳晓霞. 腐蚀科学与防腐技术, 2007,19, 265.]
(29) Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Sugimoto, T.; Matsui,M.; Kim, H. S.; Allred, G. D.; Zajicek, J.; Kotani, Y. Energy Environ. Sci. 2012, 5, 5941.

[1]	王丹,丁迅雷,廖珩璐,戴佳钰. 单个金或银原子掺杂的氧化钒团簇上的甲烷活化反应[J]. 物理化学学报, 2019, 35(9): 1005-1013.
[2]	胡媛媛,王从洋. 双金属促进的均相碳氢键活化反应[J]. 物理化学学报, 2019, 35(9): 913-922.
[3]	单春晖,白若鹏,蓝宇. 过渡金属参与C―H键切断模式的理论研究进展[J]. 物理化学学报, 2019, 35(9): 940-953.
[4]	陈世豪,王明,姜雪峰. C―H官能化构建硫醚[J]. 物理化学学报, 2019, 35(9): 954-967.
[5]	陈强,姜利学,李海方,陈娇娇,赵艳霞,何圣贵. 钒硼双原子阳离子活化甲烷研究[J]. 物理化学学报, 2019, 35(9): 1014-1020.
[6]	赵梦迪,陆文军. 普通烷烃C―H键的活化官能化[J]. 物理化学学报, 2019, 35(9): 977-988.
[7]	韩萌茹,周亚男,周旋,储伟. 通过g-C₃N₄担载MNi₁₂ (Fe, Co, Cu, Zn)纳米团簇调节甲烷化[J]. 物理化学学报, 2019, 35(8): 850-857.
[8]	程振杰, 毛亚云, 董庆雨, 金锋, 沈炎宾, 陈立桅. 氟代碳酸乙烯酯添加剂对钠离子电池正极的影响[J]. 物理化学学报, 2019, 35(8): 868-875.
[9]	王倩倩,刘大军,何兴权. 基于金属有机框架衍生的Fe-N-C纳米复合材料作为高效的氧还原催化剂[J]. 物理化学学报, 2019, 35(7): 740-748.
[10]	陈东,岳昕阳,李璕琭,吴晓京,周永宁. 锂硒电池正极材料的研究进展[J]. 物理化学学报, 2019, 35(7): 667-683.
[11]	王露,孙威,刘超. 同核铁系双金属络合物及其在均相催化体系中的应用[J]. 物理化学学报, 2019, 35(7): 697-708.
[12]	杨晓冬,陈驰,周志有,孙世刚. 碳基非贵金属氧还原电催化剂的活性位结构研究进展[J]. 物理化学学报, 2019, 35(5): 472-485.
[13]	刘艳芳,胡兵,尹雅芝,刘国亮,洪昕林. 无表面活性剂条件下一锅法制备金属/氧化锌复合材料用于催化二氧化碳加氢制甲醇反应[J]. 物理化学学报, 2019, 35(2): 223-229.
[14]	神祥艳,何建江,王宁,黄长水. 石墨炔在电化学储能器件中的应用[J]. 物理化学学报, 2018, 34(9): 1029-1047.
[15]	李勇军,李玉良. 石墨炔的化学修饰及功能化[J]. 物理化学学报, 2018, 34(9): 992-1013.