集流体对可充镁电池电解液电化学性能的影响

doi:10.3866/PKU.WHXB201208032

物理化学学报 >> 2012, Vol. 28 >> Issue (11): 2625-2631.doi: 10.3866/PKU.WHXB201208032

集流体对可充镁电池电解液电化学性能的影响

陈强, 努丽燕娜, 杨军, 凯丽比努尔·克日木, 王久林

上海交通大学化学化工学院, 上海 200240

收稿日期:2012-06-20 修回日期:2012-08-02 发布日期:2012-10-17
通讯作者: 努丽燕娜 E-mail:nlyn@sjtu.edu.cn
基金资助:
国家自然科学基金(20603022, 20973112)资助项目

Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries

CHEN Qiang, NULI Yanna, YANG Jun, KAILIBINUER Kerimu, WANG Jiulin

School of Chemistry and Chemical Technology, Shanghai Jiaotong University, Shanghai 200240, P. R. China

Received:2012-06-20 Revised:2012-08-02 Published:2012-10-17
Supported by:
The project was supported by the National Natural Science Foundation of China (20603022, 20973112).

摘要/Abstract

摘要：

系统研究了铂、镍、不锈钢(SS)、铜、铝五种金属集流体和碳纤维、石墨箔、碳布三种碳纸集流体对“一代” (Mg(AlCl₂BuEt)₂/THF)、“二代” ((PhMgCl)₂-AlCl₃/THF)可充镁电池电解液阳极氧化分解电位和镁沉积-溶出性能的影响。金属镍、不锈钢、铜、铝作为可充镁电池正极的集流体时, 充电至一定电压时自身均会发生腐蚀。其中, 镍和不锈钢可用作充电电压在2.1V(vs Mg/Mg²⁺)以下正极材料的集流体; 铜可用作充电电压在1.8V(vs Mg/Mg²⁺)以下正极材料的集流体。碳集流体比金属集流体具有更高的稳定性, 其中, 碳布作为集流体, 适用于充电电压在2.25V(vs. Mg)(对“一代”电解液)和2.95V(vs Mg/Mg²⁺)(对“二代”电解液)以下的正极材料。

关键词: 可充镁电池, 集流体, 金属, 碳纸, 电解液

Abstract:

The effects of metal (platinum, nickel, stainless steel (SS), copper and aluminum) and carbon paper (carbon fiber, graphite foil and carbon cloth) current collectors on the anodic stability and magnesium deposition-dissolution of the electrolytes (Mg(AlCl₂BuEt)₂/THF and (PhMgCl)₂-AlCl₃/THF) for rechargeable magnesium batteries were studied by cyclic voltammogram and constant current deposition-dissolution measurements. Nickel, stainless steel, copper and aluminum current collectors occur corrosion upon charging process. Nickel or stainless steel exhibits a higher stability, which can be used as the current collector for the cathode materials with a charging voltage under 2.1V (vs Mg/Mg²⁺). While copper is suitable for the cathode with a charging voltage under 1.8V (vs Mg/Mg²⁺). Furthermore, carbon paper current collectors have a higher anodic stability than metals. Carbon cloth is appropriate for the cathode materials with a charging voltage under 2.25V (vs Mg/Mg²⁺) in Mg(AlCl₂BuEt)₂/THF and 2.95V (vs Mg/Mg²⁺) in (PhMgCl)₂-AlCl₃/THF.

Key words: Rechargeable magnesium battery, Current collector, Metal, Carbon paper, Electrolyte

MSC2000:

O646

陈强, 努丽燕娜, 杨军, 凯丽比努尔·克日木, 王久林. 集流体对可充镁电池电解液电化学性能的影响[J]. 物理化学学报, 2012, 28(11): 2625-2631.

CHEN Qiang, NULI Yanna, YANG Jun, KAILIBINUER Kerimu, WANG Jiulin. Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries[J]. Acta Phys. -Chim. Sin., 2012, 28(11): 2625-2631.

参考文献

(1) Gregory, T. D.; Hoffman, R. J.;Winterton, R. C. J. Electrochem. Soc. 1990, 137, 775. doi: 10.1149/1.2086553
(2) Aurbach, D.; Lu, Z.; Schechter, A.; Gofer, Y.; Gizbar, H.;Turgeman, R.; Cohen, Y.; Moshkovich, M.; Levi, E. Nature2000, 407, 724. doi: 10.1038/35037553
(3) Yuan, H. T.;Wu, F.;Wu, X. L.; Li, Q. Battery Bimonthly 2002,32, 14. [袁华堂, 吴峰, 武绪丽, 李强. 电池, 2002, 32,14.]
(4) Shen, J.; Peng, B.; Tao, Z. L.; Chen, J. Progess in Chemistry2012, 22, 515. [沈健, 彭博, 陶占良, 陈军. 化学进展,2010, 22, 515.]
(5) Zheng, Y. P.; NuLi, Y. N.; Yang, J.; Chen, Q.;Wang, J. L.Chemical Industry and Engineering Progress 2011, 30 (5),1024. [郑育培, 努丽燕娜, 杨军, 陈强, 王久林.化工进展, 2011, 30 (5), 1024.]
(6) Zhao, Q. S.; Nuli, Y. N.; Guo, Y. S.; Yang, J.;Wang, J. L.Progress in Chemistry 2011, 23, 1598. [赵青松, 努丽燕娜,郭永胜, 杨军, 王久林. 化学进展, 2011, 23, 1598.]
(7) Aurbach, D.; Schechter, A.; Moshkovich, M.; Cohen, Y.;J. Electrochem. Soc. 2001, 148, A1004.
(8) Aurbach, D.; Gizbar, H.; Schechter, A.; Chusid, O.; Gottlieb, H.E.; Gofer, Y.; Goldberg, I. J. Electrochem. Soc. 2002, 149, A115.
(9) Gizbar, H.; Vestfrid, Y.; Chusid, O.; Gofer, Y.; Gottlieb, H. E.;Marks, V.; Aurbach, D. Organometallics 2004, 23, 3826. doi: 10.1021/om049949a
(10) Vestfried, Y.; Chusid, O.; Gofer, Y.; Aped, P.; Aurbach, D.Organometallics 2007, 26, 3130. doi: 10.1021/om061076s
(11) Viestfried, Y.; Levi, M. D.; Gofer, Y.; Aurbach, D.J. Electroanal. Chem. 2005, 576, 183. doi: 10.1016/j.jelechem.2004.09.034
(12) Aurbach, D.; Suresh, G. S.; Levi, E.; Mitelman, A.; Mizrahi, O.;Chusid, O.; Brunelli, M. Adv. Mater. 2007, 19, 4260. doi: 10.1002/(ISSN)1521-4095
(13) Mizrahi, O.; Amir, N.; Pollak, E.; Chusid, O.; Marks, V.;Gottlieb, H.; Larush, L.; Zinigrad, E.; Aurbach, D.J. Electrochem. Soc. 2008, 155, A103.
(14) Pour, N.; Gofer, Y.; Major, D. T.; Aurbach, D. J. Am. Chem. Soc.2011, 133, 6270. doi: 10.1021/ja1098512
(15) Arora, P.; White, R. E.; Doyle, M. J. Electrochem. Soc. 1998,145, 3647. doi: 10.1149/1.1838857
(16) Tarascon, J.; Guyomard, D. Solid State Ionics 1994, 69, 293.doi: 10.1016/0167-2738(94)90418-9
(17) Kanamura, K.; Toriyama, S.; Shiraishi, S.; Takehara, Z.J. Electrochem. Soc. 1995, 142, 1383. doi: 10.1149/1.2048586
(18) Dahn, J. R; Fuller, E.W.; Obrovac, M.; Von Sacken, U. Solid State Ionics 1994, 69, 265. doi: 10.1016/0167-2738(94)90415-4
(19) Amatucci, G.; Tarascon, J.; Klein, L. Solid State Ionics 1996,83, 167.
(20) Morita, M.; Shibata, T.; Yoshimoto, N.; Ishikawa, M.Electrochim. Acta 2002, 47, 2787. doi: 10.1016/S0013-4686(02)00164-0
(21) Kanamura, K. J. Power Sources 1999, 81-82, 123.
(22) Peng, C. X. Research on the Compatibility between CurrentCollectors and New Ionic Liquid Electrolytes for LithiumSecondary Batteries. Ph. D. Dissertation, Shanghai JiaotongUniversity, Shanghai, 2008. [彭成信. 锂离子电池集流体与新型离子液体电解液的相容性及界面电化学行为研究[D].上海: 上海交通大学, 2008.]
(23) Ni, J. F.; Zhou, H. H.; Chen, J. T.; Zhang, X.Y. Battery Bimonthly2005, 35, 128. [倪江锋, 周恒辉, 陈继涛, 张新祥. 电池,2005, 35, 128.]
(24) Iwakura, C.; Fukumoto, Y.; Inoue, H.; Ohashi, S.; Kobayashi,S.; Tada, H.; Abe, M. J. Power Sources 1997, 68, 3013.
(25) Dai, Y. H.; Zhou, Y. M.;Wang, Q.; Tang, Y.W.; Lu, T. H.; Shen,T. Chinese Battery Industry 2007, 12, 31. [戴跃华, 周益明,王青, 唐亚文, 陆天虹, 沈涛. 电池工业, 2007, 12, 31.]
(26) Aurbach, D.; Turgeman, R.; Chusid, O.; Gofer, Y. Electrochem. Commun. 2001, 3, 252. doi: 10.1016/S1388-2481(01)00148-5
(27) Liebenow, C.; Yang, Z.; Lobitz, P. Electrochem. Commun. 2000,2, 641. doi: 10.1016/S1388-2481(00)00094-1
(28) Tang, Z, Y.; He, Y. B.; Liu, Y. G.; Liu, Q.; Yang, X. X. Corrosion Science and Protection Technology 2007, 19, 265. [唐致远,贺艳兵, 刘元刚, 刘强, 阳晓霞. 腐蚀科学与防腐技术, 2007,19, 265.]
(29) Muldoon, J.; Bucur, C. B.; Oliver, A. G.; Sugimoto, T.; Matsui,M.; Kim, H. S.; Allred, G. D.; Zajicek, J.; Kotani, Y. Energy Environ. Sci. 2012, 5, 5941.

[1]	李聪明, 陈阔, 王晓月, 薛楠, 杨恒权. 探究Cu/ZnO相互作用对CO₂加氢制甲醇反应性能的影响[J]. 物理化学学报, 2021, 37(5): 2009101 -0 .
[2]	华凯敏, 刘晓放, 魏百银, 张书南, 王慧, 孙予罕. 过渡金属催化CO₂/H₂参与的羰基化研究进展[J]. 物理化学学报, 2021, 37(5): 2009098 -0 .
[3]	邹广锐兴, 陈梓铭, 黎振超, 叶轩立. 蓝光钙钛矿发光二极管：机遇与挑战[J]. 物理化学学报, 2021, 37(4): 2009002 -0 .
[4]	衡永丽, 谷振一, 郭晋芝, 吴兴隆. 水系锌离子电池用钒基正极材料的研究进展[J]. 物理化学学报, 2021, 37(3): 2005013 -0 .
[5]	李琳, 沈水云, 魏光华, 章俊良. 基于血红素衍生的中空非贵金属催化剂氧还原反应电催化活性[J]. 物理化学学报, 2021, 37(3): 1911011 -0 .
[6]	吴晨, 周颖, 朱晓龙, 詹忞之, 杨汉西, 钱江锋. 锂金属电池用高浓度电解液体系研究进展[J]. 物理化学学报, 2021, 37(2): 2008044 -0 .
[7]	朱高龙, 赵辰孜, 袁洪, 南皓雄, 赵铂琛, 侯立鹏, 何传新, 刘全兵, 黄佳琦. 基于局部高盐界面润湿策略构筑的固态金属锂软包电池[J]. 物理化学学报, 2021, 37(2): 2005003 -0 .
[8]	康丹苗, NoamHart, 肖沐野, JohnP. Lemmon. 锂金属电池研究中对称电池的短路现象[J]. 物理化学学报, 2021, 37(2): 2008013 -0 .
[9]	张自博, 邓伟, 周旭峰, 刘兆平. 稳定锂电化学沉积和溶解行为的LiC₆异质微结构界面层[J]. 物理化学学报, 2021, 37(2): 2008092 -0 .
[10]	王志达, 冯元宬, 卢松涛, 王锐, 秦伟, 吴晓宏. 利用原位氟化保护层改善三维锡锂合金/碳纸负极贫电解液下性能[J]. 物理化学学报, 2021, 37(2): 2008082 -0 .
[11]	华广斌, 樊晏辰, 张千帆. 计算模拟在锂金属负极研究中的应用[J]. 物理化学学报, 2021, 37(2): 2008089 -0 .
[12]	关俊, 李念武, 于乐. 人工界面层在金属锂负极中的应用[J]. 物理化学学报, 2021, 37(2): 2009011 -0 .
[13]	钱华明, 李喜飞. 功能化固态电解质膜改性锂金属负极的研究进展[J]. 物理化学学报, 2021, 37(2): 2008092 -0 .
[14]	何一涛, 丁飞, 林立, 王志红, 吕喆, 张耀辉. 电极界面浓差极化对锂金属沉积的影响[J]. 物理化学学报, 2021, 37(2): 2009001 -0 .
[15]	岳昕阳, 马萃, 包戬, 杨思宇, 陈东, 吴晓京, 周永宁. 金属锂负极失效机制及其先进表征技术[J]. 物理化学学报, 2021, 37(2): 2005012 -0 .

集流体对可充镁电池电解液电化学性能的影响

Effects of Current Collectors on the Electrochemical Performance of Electrolytes for Rechargeable Magnesium Batteries

PDF

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0