### 基于电化学方法研究以铜和银为电极的对苯二甲酸单分子结电导

1. 浙江师范大学物理化学研究所, 浙江省固体表面反应化学重点实验室, 浙江 金华 321004
• 收稿日期:2014-09-30 修回日期:2014-10-22 发布日期:2014-12-25
• 通讯作者: 周小顺 E-mail:xszhou@zjnu.edu.cn
• 基金资助:

国家自然科学基金(21003110, 21273204)和浙江省科技厅(2014C37102)资助项目

### Single-Molecule Junction Conductance of Terephthalic Acid Contacting Ag and Cu Electrodes Measured by an Electrochemical Method

HAN Di, HONG Ze-Wen, LI Dong-Fang, ZHENG Ju-Fang, WANG Ya-Hao, ZHOU Xiao-Shun

1. Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, Zhejiang Province, P. R. China
• Received:2014-09-30 Revised:2014-10-22 Published:2014-12-25
• Contact: ZHOU Xiao-Shun E-mail:xszhou@zjnu.edu.cn
• Supported by:

The project was supported by the National Natural Science Foundation of China (21003110, 21273204) and Planned Science and Technology Project of Zhejiang Province, China (2014C37102).

Abstract:

The single-molecule junction conductance of terephthalic acid binding to Cu andAg electrodes was measured by an electrochemical jump-to-contact scanning tunneling microscopy break junction (ECSTM-BJ) approach. The Cu andAg electrodes were formed in-situ, via electrodeposition froma solution. The conductance histograms of the single-molecule junctions formed via the binding of terephthalic acid to the Cu and Ag electrodes showed a well-defined shape, in the absence of any data selection. The single-molecule junction conductance values for the terephthalic acid binding to the Cu electrode were 11.5 nS (high conductance) and 4 nS (lowconductance), while the high and lowconductance values for theAg electrode were 10.3 and 3.8 nS, respectively. The high conductance values were typically approximately three times larger than the low conductance values, for both the Cu and the Ag electrodes. The conductance (G) value for the terephthalic acid followed the order of GCu>GAg, which indicated the different electronic coupling efficiencies between the molecule and electrodes. In contrast with the single set conductance value measured for alkanedicarboxylic acid using the same approach, two set conductance values were found for the terephthalic acid junctions with the Cu and Ag electrodes. These results illustrated the important role of the backbone of the chain in conductance measurements. The present work demonstrated the influence of the electrode and the molecular structure on the single-molecule junction conductance.

MSC2000:

• O646