物理化学学报 >> 2015, Vol. 31 >> Issue (4): 595-611.doi: 10.3866/PKU.WHXB201502023

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有机金属酞菁类化合物及其非线性光限幅特性

陈军1,2, 王双青2, 杨国强2   

  1. 1 江西理工大学材料科学与工程学院, 江西赣州341000;
    2 中国科学院化学研究所光化学重点实验室, 北京国家分子科学中心, 北京100190
  • 收稿日期:2014-12-08 修回日期:2015-02-02 发布日期:2015-04-03
  • 通讯作者: 王双青, 杨国强 E-mail:g1704@iccas;gqyang@iccas.ac.cn
  • 基金资助:

    国家重点基础研究发展规划项目(973) (2011CBA00905)和国家自然科学基金(21261160488)资助

Nonlinear Optical Limiting Properties of Organic Metal Phthalocyanine Compounds

CHEN Jun1,2, WANG Shuang-Qing2, YANG Guo-Qiang2   

  1. 1 School of Materials Science and Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi Province, P. R. China;
    2 Beijing National Laboratory for Molecular Sciences, Key Laboratory of Photochemistry, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China
  • Received:2014-12-08 Revised:2015-02-02 Published:2015-04-03
  • Contact: WANG Shuang-Qing, YANG Guo-Qiang E-mail:g1704@iccas;gqyang@iccas.ac.cn
  • Supported by:

    The project was supported by the National Key Basic Research Program of China (973) (2011CBA00905) and National Natural Science Foundation of China (21261160488).

摘要:

随着激光技术的快速发展, 激光武器的性能也越来越优越, 所造成的危害也越来越大, 各国开始加大力度对激光防护材料进行研究. 酞菁化合物具有限幅窗口宽、限幅效果明显、响应迅速等特点, 是一类非常具有应用前景的光限幅材料. 当前, 制备出限幅性能好、稳定性强的酞菁光限幅材料成为激光防护材料领域中的研究热点. 本文评述和总结了近几年在酞菁光限幅材料方面开展的系统研究工作, 首先介绍了酞菁化合物实现光限幅效应的机制, 并在此基础上详细分析了影响光限幅效应的因素以及光限幅器件化过程对酞菁光物理和光限幅性能的影响机理. 根据分析结果提出了在基础和应用研究方面存在的科学问题, 指出了该类型光限幅材料面临的挑战和今后的重要发展方向.

关键词: 酞菁, 非线性效应, 光限幅机制, 光限幅器件

Abstract:

With the rapid development of laser technology, laser weapons that can cause increasing amounts of harm to humans are emerging. In recent years, studies on optical limiting (OL) materials have been carried out with great efforts among countries. Phthalocyanine (Pc) compound exhibits characteristics of broad OL threshold, obvious limiting effect, and fast response. Because of these characteristics, Pc is considered as a very promising OLmaterial that is significant in laser protectivematerials' research, which currently focuses on increasing performance and stability. This paper reviews and summarizes the current knowledge of Pc OL materials. First, the mechanism of the OL effect of Pc compounds is introduced, and then followed by a detailed analysis of the factors influencing the OL effect and process, and the influence on the photophysical and OL performance of Pc materials. The analysis highlights problems to be solved and proposes the future direction for Pcmaterials' research.

Key words: Phthalocyanine, Nonlinear effect, Optical limiting mechanism, Optical limiting device

MSC2000: 

  • O644