物理化学学报 >> 2016, Vol. 32 >> Issue (3): 771-779.doi: 10.3866/PKU.WHXB201601043

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卤代苯溶剂对镓咔咯配合物光物理性质的影响:外重原子效应

占轩1,赵芳2,张蕾2,*(),吕标彪3,彭素红1,应晓3,王惠2,*(),刘海洋1,2,*()   

  1. 1 华南理工大学化学系, 广州 510641
    2 中山大学光电材料与技术国家重点实验室, 广州 510275
    3 华南理工大学应用物理系, 广州 510641
  • 收稿日期:2015-11-03 发布日期:2016-03-04
  • 通讯作者: 张蕾,王惠,刘海洋 E-mail:zhlei28@mail.sysu.edu.cn;stswh@mail.sysu.edu.cn;chhyliu@scut.edu.cn
  • 基金资助:
    国家自然科学基金(21171057, 21371059);国家重点基础研究发展规划项目((973)(2013CB922403));中山大学光电材料与技术国家重点实验室开放基金(OEMT-2015-KF-05)

Influence of Halogenated Benzene Solvents on the Photophysical Properties of Gallium Corroles: the External Heavy Atom Effect

Xuan ZHAN1,Fang ZHAO2,Lei ZHANG2,*(),Biao-Biao LÜ3,Su-Hong PENG1,Xiao YING3,Hui WANG2,*(),Hai-Yang LIU1,2,*()   

  1. 1 Department of Chemistry, South China University of Technology, Guangzhou 510641, P. R. China
    2 State Key Laboratory of Optoelectronics Materials and Technologies, Sun-Yat Sen University, Guangzhou 510275, P. R. China
    3 Department of Applied Physics, South China University of Technology, Guangzhou 510641, P. R. China
  • Received:2015-11-03 Published:2016-03-04
  • Contact: Lei ZHANG,Hui WANG,Hai-Yang LIU E-mail:zhlei28@mail.sysu.edu.cn;stswh@mail.sysu.edu.cn;chhyliu@scut.edu.cn
  • Supported by:
    the National Natural Science Foundation of China(21171057, 21371059);National Key Basic Research Program of China((973)(2013CB922403));Open Fund of State Key Laboratory of Opto-Electronic Material and Technologies of SunYat-Sen University, China(OEMT-2015-KF-05)

摘要:

利用紫外-可见光谱、稳态和时间分辨荧光光谱以及飞秒瞬态吸收光谱探测了不同卤代苯溶剂对三种五氟苯基取代的镓咔咯(1-Ga、2-Ga、3-Ga)光物理性质的影响,结果表明卤代苯溶剂的色散力对于镓咔咯电子光谱吸收峰位置的影响起着主要作用;溶剂外重原子效应能显著降低镓咔咯的荧光量子产率。飞秒瞬态吸收光谱表明,光激发下,镓咔咯与卤代苯溶剂之间可发生电子转移反应,溶剂的重原子效应可以减缓电荷分离态复合物电荷重组速率。

关键词: 咔咯, 镓, 卤代苯溶剂, 重原子效应, 光物理性质

Abstract:

The photophysical properties of pentafluorophenyl-substituted gallium corroles in halogenated benzenes were investigated using ultraviolet-visible (UV-Vis), steady-state, time-resolved fluorescence, and femtosecond transient absorption spectroscopies. The results showed that the absorption maximum wavelength of the gallium corroles was mainly related to the dispersion force of the halogenated benzene solvents. The external heavy atom effect of halogenated benzenes may markedly lower the fluorescence quantum yield of gallium corrole complexes. Photoinduced electron transfer between the gallium corroles and halogenated benzene solvents was detected by femtosecond transient absorption spectroscopy. The experimental evidence showed that the heavy atom effect of the solvent might lower the charge recombination rate of charge-separated gallium corrole-solvent complexes.

Key words: Corrole, Gallium, Halogenated benzene solvent, External heavy atom effect, Photophysical property

MSC2000: 

  • O641.06