物理化学学报 >> 2016, Vol. 32 >> Issue (10): 2447-2461.doi: 10.3866/PKU.WHXB201607141

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金属卟啉二维纳米晶的制备及其光电性能

石乃恩1,*(),宋传远1,张俊1,黄维1,2,*()   

  1. 1 南京邮电大学信息材料与纳米技术研究院,江苏省有机电子与信息显示重点实验室,南京210023
    2 南京工业大学先进材料研究院,江苏-新加坡有机/生物电子与信息显示联合研究中心,南京211816
  • 收稿日期:2016-05-31 发布日期:2016-09-30
  • 通讯作者: 石乃恩,黄维 E-mail:iamneshi@njupt.edu.cn;wei-huang@njtech.edu.cn
  • 作者简介:石乃恩,南京邮电大学材料科学与工程学院副教授,硕士生导师。主要研究方向为配位聚合物及有机功能纳米材料的合成与纳米光电器件。|宋传远,南京邮电大学材料科学与工程学院(信息材料与纳米技术研究院)硕士研究生。主要研究方向:π-共轭类配体二维纳米材料的合成、表征及应用。|张俊,南京邮电大学材料科学与工程学院(信息材料与纳米技术研究院)硕士研究生。研究方向:金属卟啉二维纳米晶的光电性能。|黄维,中国科学院院士,南京工业大学校长、博导,有机光电子学家。俄罗斯科学院及英国谢菲尔德大学名誉博士,英国皇家化学会会士。研究领域为有机光电子学、柔性电子学。
  • 基金资助:
    国家自然科学基金(21471082);国家自然科学基金(21101095);国家自然科学基金(61136003);江苏高校优势学科建设工程项目(PAPD,YX03001);教育部创新团队(IRT1148);江苏省自然科学基金(BM2012010);江苏省有机电子和信息显示协同创新中心项目

Preparation and Optoelectronic Applications of Two-Dimensional Nanocrystals Based on Metallo-Porphyrins

Nai-En SHI1,*(),Chuan-Yuan SONG1,Jun ZHANG1,Wei HUANG1,2,*()   

  1. 1 Key Laboratory for Organic Electronics and Information Displays and Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing University of Posts & Telecommunications, Nanjing 210023, P. R. China
    2 Key Laboratory of Flexible Electronics & Institute of Advanced Materials, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, P. R. China
  • Received:2016-05-31 Published:2016-09-30
  • Contact: Nai-En SHI,Wei HUANG E-mail:iamneshi@njupt.edu.cn;wei-huang@njtech.edu.cn
  • Supported by:
    National Natural Science Foundation of China(21471082);National Natural Science Foundation of China(21101095);National Natural Science Foundation of China(61136003);Priority Academic Program Development of Jiangsu Higher Education Institutions, China(PAPD,YX03001);Ministry of Education of China(IRT1148);Natural Science Foundation of Jiangsu Province, China(BM2012010);Synergetic Innovation Center for Organic Electronics and Information Displays, China

摘要:

金属卟啉是一种重要的金属-有机复合物,在光电转换器件、催化、传感、医学等领域有着广阔的应用前景。对无机二维纳米材料(石墨烯或过渡金属硫属化合物等)的广泛研究促使金属-有机二维纳米材料成为当前的研究热点之一。本文针对金属-有机以及卟啉二维纳米材料的研究现状,在简要回顾金属-有机二维纳米材料发展历史的基础上,详细总结了金属卟啉单分散二维纳米晶和二维薄膜的制备方法,综述了其当前在太阳能电池、光电催化以及光学传感等方面的应用,最后讨论了金属卟啉二维纳米材料当前面临的研究问题及未来可能的发展方向。

关键词: 卟啉, 二维材料, 纳米片, 纳米薄膜, 光电性质

Abstract:

Metalloporphyrins are a class of metal-organic complexes that exhibit a wide range of interesting properties with prosperous applications in photoelectric conversion devices, catalysis, sensors and medicines. Besides inorganic two-dimensional (2D) materials (e.g., graphene and transitional metal dichalcogenide nanosheets), two-dimensional metal-organic nanosheets have also attracted considerable attention in recent years as interesting materials. Based on the rapid progress of two-dimensional metal-organic and porphyrinoid nanomaterials, this review aims to provide a brief review of the history of two-dimensional metal-organic nanomaterials, followed by a detailed summary of the synthetic methods used to prepare free-standing 2D nanosheets as well as 2D thin film of metalloporphyrins. We have also provided an up-to-date review of the applications of these materials in solar cells, photo- and electric catalysts as well as optical sensors, and a discussion pertaining to the problems associated with the synthesis, properties, and possible applications of metalloporphyrin 2D materials.

Key words: Porphyrin, Two-dimensional material, Nanosheet, Nano-thin film, Optoelectric property

MSC2000: 

  • O648