物理化学学报 >> 2017, Vol. 33 >> Issue (5): 869-885.doi: 10.3866/PKU.WHXB201702088

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基于类石墨烯二维材料的析氢反应电催化剂的研究进展

凌崇益,王金兰*()   

  • 收稿日期:2016-12-20 发布日期:2017-04-20
  • 通讯作者: 王金兰 E-mail:jlwang@seu.edu.cn
  • 作者简介:凌崇益,男,1990年出生,东南大学物理系2015级博士研究生。主要从事电解水制氢的二维材料催化剂的研究与设计|王金兰,女,1973年出生,东南大学物理学院教授、博士生导师。东南大学特聘教授、国家杰出青年基金获得者。长期从事低维材料物性的理论研究,先后主持国家自然科学基金面上项目6项、教育部博士点基金(博导类)2项
  • 基金资助:
    国家自然科学基金(21525311);国家自然科学基金(21373045);国家自然科学基金(11404056);江苏省自然科学基金(BK20130016);高等学校博士学科点专项科研基金(20130092110029);东南大学优秀博士学位论文基金(YBJJ1670)

Recent Advances in Electrocatalysts for the Hydrogen Evolution Reaction Based on Graphene-Like Two-Dimensional Materials

Chong-Yi LING,Jin-Lan WANG*()   

  • Received:2016-12-20 Published:2017-04-20
  • Contact: Jin-Lan WANG E-mail:jlwang@seu.edu.cn
  • Supported by:
    National Natural Science Foundation of China(21525311);National Natural Science Foundation of China(21373045);National Natural Science Foundation of China(11404056);National Natural Science of Jiangsu Province, China(BK20130016);Specialized Research Fund for the Doctoral Program of Higher Education, China(20130092110029);Scientific Research Foundation of Graduate School of Southeast University, China(YBJJ1670)

摘要:

利用可再生能源产生的电能电解水制取氢气,被认为是下一代清洁能源的最佳选择之一。然而,通过电解水可持续的产生氢气需要高活性的催化剂来使得反应有效地进行。基于类石墨烯二维材料的析氢反应电催化剂展现出巨大的潜力,因而备受关注。本文主要结合我们课题组近期在析氢反应电催化剂方面的研究,介绍了类石墨烯二维材料的析氢反应电催化剂的研究进展,主要包括过渡金属二硫族化合物、前过渡金属碳化物(MXenes)以及硼单层纳米片等。最后总结和展望了析氢反应电催化剂所面临的挑战与未来发展方向。

关键词: 电解水, 析氢反应, 二维材料, 催化剂

Abstract:

Hydrogen produced from electrochemical water-splitting driven by renewable resource-derived electricity is considered a promising candidate for clean energy. However, sustainable hydrogen production from water splitting requires highly active catalysts to make the process efficient. Catalysts based on graphene-like two-dimensional (2D) materials present great potential in the hydrogen evolution reaction (HER) and thus gain attention. In this review, which is a combination of our recent works, we highlight research efforts towards electrocatalysts for the HER based on 2D materials including transition metal disulfides, MXenes, and boron monolayers. Finally, we summarize the challenges and prospects for future development of electrocatalysts for the hydrogen evolution reaction.

Key words: Water electrolysis, Hydrogen evolution reaction, Two-dimensional materials, Catalyst

MSC2000: 

  • O643