物理化学学报 >> 2017, Vol. 33 >> Issue (11): 2153-2172.doi: 10.3866/PKU.WHXB201705313

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磷烯的制备、结构、性质及器件应用

朱晋潇,刘晓东,薛敏钊*(),陈长鑫*()   

  • 收稿日期:2017-03-29 发布日期:2017-08-25
  • 通讯作者: 薛敏钊,陈长鑫 E-mail:mzxue@sjtu.edu.cn;chen.c.x@sjtu.edu.cn
  • 作者简介:朱晋潇,男,1995年出生,上海交通大学硕士研究生。主要研究方向为碳纳米管、磷烯等低维材料的制备、器件与应用|刘晓东,男,上海交通大学电子科学与技术专业博士生。研究方向为低维半导体纳米材料的组装、改性及电子器件研究|薛敏钊,男,上海交通大学副教授、薄膜与微细技术教育部重点实验室客座导师,从事有机功能材料、有机/无机杂化材料及功能性乳液和涂层等的研究|陈长鑫,男,于上海交通大学获博士学位,斯坦福大学博士后;目前任教于上海交通大学、2011年起担任博士生导师。主要研究方向为基于一维和二维材料的光电和电子器件及技术
  • 基金资助:
    国家自然科学基金优秀青年科学基金项目(61622404);上海市浦江人才计划(15PJ1403300);上海市“科技创新行动计划”国际合作项目(15520720200);国家自然科学基金面上项目(61177052);全国优秀博士学位论文作者专项资金资助项目(201154);中国博士后面上基金项目(2016M601595);江苏省基础研究计划青年基金项目(BK20150364)

Phosphorene: Synthesis, Structure, Properties and Device Applications

Jin-Xiao ZHU,Xiao-Dong LIU,Min-Zhao XUE*(),Chang-Xin CHEN*()   

  • Received:2017-03-29 Published:2017-08-25
  • Contact: Min-Zhao XUE,Chang-Xin CHEN E-mail:mzxue@sjtu.edu.cn;chen.c.x@sjtu.edu.cn
  • Supported by:
    National Natural Science Foundation of China for Excellent Young Scholars(61622404);Shanghai Pujiang Talent Program(15PJ1403300);Science and Technology Innovation Action Program from the Science and Technology Commission of Shanghai Municipality, China(15520720200);National Natural Science Foundation of China(61177052);Foundation for the Author of National Excellent Doctoral Dissertation of China(201154);China Postdoctoral Science Foundation(2016M601595);Natural Science Foundation of Jiangsu Province(BK20150364)

摘要:

磷烯是继石墨烯之后一种新型的二维材料,具有优异的物理、化学和机械性能,在各类器件中具有大的应用潜力。目前对磷烯的最新制备方法、特性调控和应用的系统总结较少。本文对磷烯的制备、结构、性质、改性方法及其器件应用进行了系统的综述。首先概括了磷烯“自上而下”和“自下而上”的制备方法,对其结构和性质进行了总结,同时讨论了磷烯的修饰改性方法,最后对磷烯的器件应用进行了较详细的介绍,并在此基础上对磷烯的研究方向和前景进行了展望。

关键词: 磷烯, 材料制备, 结构表征, 器件应用

Abstract:

Phosphorene is a novel two-dimensional material that is more advanced than graphene. This material possesses excellent physical, chemical, and mechanical properties, which are useful for potential applications in a variety of electronic devices. Thus far, a comprehensive review on the latest fabrication methods, property tuning, and applications of phosphorene is lacking. Therefore, a comprehensive review of the synthetic methods, structures, properties, modification methods, and device applications of phosphorene has been presented. The preparation strategies of phosphorene including top-bottom and bottom-up methods have been introduced, followed by a summary of its structure and properties. The modification methods of phosphorene have also been discussed. Finally, the applications of phosphorene in electronic devices have been discussed in detail. Future prospects and potential research areas of phosphorene have also been presented in this review.

Key words: Phosphorene, Material synthesis, Structure characterization, Devices application

MSC2000: 

  • O641