物理化学学报 >> 2018, Vol. 34 >> Issue (4): 361-376.doi: 10.3866/PKU.WHXB201708312
所属专题： 高被引科学家专刊
维度调控策略提升铂基纳米晶氧还原催化研究进展
骆明川1, 孙英俊1,3, 秦英楠1,3, 杨勇1, 吴冬4, 郭少军1,2,*(
)
- 1 北京大学工学院材料科学与工程系，北京100871
2 北京大学工学院工程科学与新兴技术高精尖中心，北京100871
3 青岛科技大学化学与分子工程学院，山东青岛266042
4 北京大学前沿交叉学科研究院，北京100871
-
收稿日期:2017-06-30录用日期:2017-08-16发布日期:2018-01-02 -
通讯作者:郭少军 E-mail:guosj@pku.edu.cn -
作者简介:|Shaojun Guo is currently a Professor of Materials Science and Engineering with a joint appointment at Department of Energy & Resources Engineering, at College of Engineering, Peking University. He received his BSc in chemistry from Jilin University (2005), Ph.D. from Chinese Academy of Sciences (2011) with Profs. Erkang Wang and Shaojun Dong, and joined Prof. Shouheng Sun's group as a postdoctoral research associate from Jan. 2011 to Jun. 2013 at Brown University. Then, he works as a very prestigious J. Robert Oppenheimer Distinguished Fellow at Los Alamos National Laboratory. His research interests are in engineering multimetallic nanocrystals and 2D materials for catalysis, renewable energy, optoelectronics and biosensors
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基金资助:国家自然科学基金(51671003);博士后基金(2017M610022);国家重点基础研究发展计划(2016YFB0100201);资源有效利用国家重点实验室开放项目;北京大学启动项目和千人计划青年项目
Boosting Oxygen Reduction Catalysis by Tuning the Dimensionality of Pt-based Nanostructures
Mingchuan LUO1, Yingjun SUN1,3, Yingnan QIN1,3, Yong YANG1, Dong WU4, Shaojun GUO1,2,*()
- 1 Department of Materials Science & Engineering, College of Engineering, Peking University, Beijing 100871, P. R. China
2 BIC-ESAT, College of Engineering, Peking University, Beijing 100871, P. R. China
3 College of Chemistry and Molecular Engineering, Qingdao University of Science and Technology, Qingdao 266042, Shandong Province, P. R. China
4 Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, P. R. China
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Received:2017-06-30Accepted:2017-08-16Published:2018-01-02 -
Contact:Shaojun GUO E-mail:guosj@pku.edu.cn -
Supported by:the National Natural Science Foundation of China(51671003);the China Postdoctoral Science Foundation(2017M610022);the National Basic Research Program of China(2016YFB0100201);the Open Project Foundation of State Key Laboratory of Chemical Resource Engineering, the start-up supports from Peking University;the Young Thousand Talented Program, China
摘要：
燃料电池技术的商业化进程主要受制于其阴极动力学缓慢的氧还原反应(ORR)所需的高铂量电催化剂，因此急需开发更高活性的电催化剂。过去十年里，人们在提高铂基催化剂ORR活性的研究取得了极大进展。本文概述了通过结构调控提升铂基纳米晶氧还原电催化性能的最新进展，依据纳米晶的空间维度展开讨论，同时列举各类电催化材料的优缺点。基于理论和实验结果，本文重点讨论铂基纳米晶应用于氧还原电催化的构效关系，以及其对下一代电催化材料结构设计方面的潜在指导意义。最后，我们对此领域未来的研究方向做了展望。
MSC2000:
- O646
引用本文
骆明川, 孙英俊, 秦英楠, 杨勇, 吴冬, 郭少军. 维度调控策略提升铂基纳米晶氧还原催化研究进展[J]. 物理化学学报, 2018, 34(4): 361-376.
Mingchuan LUO, Yingjun SUN, Yingnan QIN, Yong YANG, Dong WU, Shaojun GUO. Boosting Oxygen Reduction Catalysis by Tuning the Dimensionality of Pt-based Nanostructures[J]. Acta Physico-Chimica Sinica, 2018, 34(4): 361-376.
Fig 1
(a) Catalytic activity as a function of d-band center position on various Pt3M catalysts. (b) Influence of the crystalline facets and electronic properties on the kinetics of ORR. HRTEM image of Pt3Ni (c) octahedrons and (d) icosahedrons. (e) Catalytic activities of polycrystalline Pt5M electrocatalysts as a function of corresponding lattice parameters. (a) Reprinted with permission from Ref.31. (b) Reprinted with permission from Ref.32. (c, d) Reprinted with permission from Ref.62. (e) Reprinted with permission from Ref.45."
Fig 2
Representative (a) STEM and (b) TEM images of the hierarchical Pt3Co NWs. (c) Comparison of specific and mass activities on various catalysts. (d) The changes on specific and mass activities of the hierarchical Pt3Co NWs/C catalyst before and after 10000, 15000 and 20000 potential cycles. (a, b) Reprinted with permission from Ref.68. (c, d) Reprinted with permission from Ref.69."
Fig 3
(a) Comparison of specific activities of different catalysts at 0.9 and 0.95 V vs RHE. (b) Polarization curves of the FePt NWs before and after 4000 potential cycles. Representative STEM (c and e) and HRTEM (d and f) images of subnanometer PtCo and PtNiCo NWs. HRTEM images (g–i) of the Pt/NiO core/shell nanowires, the PtNi alloy nanowires, and the J-PtNWs supported on carbon, respectively. (a, b) Reprinted with permission from Ref.70. (c–f) Reprinted with permission from Ref.72. (g–i) Reprinted with permission from Ref.73."
Fig 4
(a) SEM and (b) TEM images of PtPd NTs (inset shows the electron diffraction pattern). (c) Loss of electrochemical surface areas of Pt/C, platinum-black and Pt NTs with CV cycles. (d) ORR curves of Pt/C, platinum black, Pt NTs and PdPt NTs. Reprinted with permission from Ref.75."
Fig 5
(a) TEM image of PtPb nanoplates. (b) A model of one single hexagonal nanoplate and HAADF-STEM image from in-plate view. (c) ORR polarization curves and (d) specific and mass activities of different catalysts. Inset in (c) is the CVs of different catalysts. Reprinted with permission from Ref.80."
Fig 6
(a) TEM and (b) HAADF-STEM images of nanocages. (c) High-resolution HAADF-STEM image taken from the region boxed in (b), showing a wall thickness of six atomic layers. (d) EDS elemental mapping of Pt and Pd for two nanocages. (e) Mass activities of the catalysts at 0.9 V vs RHE. (f) Mass activities of the catalysts before and after accelerated durability test. Reprinted with permission from Ref.83."
Fig 7
(a) Schematic illustrations and corresponding TEM images of the samples obtained at four representative stages during the evolution process from polyhedra to nanoframes. Specific activities (b) and mass activities (c) measured at 0.95 V vs RHE, and improvement factors vs Pt/C catalysts. Reprinted with permission from Ref.87."
Fig 8
(a) HRTEM of 15 nm np-NiPt nanoparticle. (b) Particle size distributions of as-received PtNi3 catalyst, Air-D-PtNi3 and N2-D-PtNi3 catalyst. (c) Correlations between particle size, composition, and porosity in the three catalysts, where the horizontal dot lines represent the average compositions. (d) Cartoon illustrating the key components: the nucleus of the catalyst is a high surface area nanoporous nanoparticle, which allows the particle to be encapsulated by an IL. (a) Reprinted with permission from Ref.38. (b) Reprinted with permission from Ref.92. (c) Reprinted with permission from Ref.40. (d) Reprinted with permission from Ref.95."
Fig 9
(a) TEM and (b) HRTEM images recorded from Pt-Pb nanodentrites. (c) ORR polarization curves for the Pd-Pt nanodendrites, Pt/C catalyst and Pt black. (d) Mass activity at 0.9 V vs RHE for these three catalysts. Reprinted with permission from Ref.99."
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