物理化学学报 >> 1985, Vol. 1 >> Issue (06): 571-574.doi: 10.3866/PKU.WHXB19850611

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四氢萘热解中间产物及其反应机理的进一步研究

杨晓林; 杨惠星; 韩德刚   

  1. 北京大学化学系
  • 收稿日期:1984-12-12 修回日期:1985-03-11 发布日期:1985-12-15

THE SDUDY OF THE INTERMEDIATES REACTIONS AND THE REACTION MECHANISM IN THEE THERMOLYSIS OF TETRALINE

Yang Xiaolin; Yang Huixing; Han Degang   

  1. Chemistry Department of Peking University
  • Received:1984-12-12 Revised:1985-03-11 Published:1985-12-15

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Abstract: In order to understand more clearly the reaction mechanism in the thermolysis of tertraline, thermal decomposition of some intermediates such as 1-methylindan and butylbenzene were studied.
It follows from the experimental results that the thermolysis of 1-methylindan and butylbenzene proceeds as
The thermolysis of tetraline was affected signficantly when some free radical initiator was added.
These results give not only some enligntenments for elucidating the real paths of tetraline thermolysis but also proofs of some reaction steps in the reaction mechanism.