物理化学学报 >> 1987, Vol. 3 >> Issue (04): 435-439.doi: 10.3866/PKU.WHXB19870419

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Cu-Zn-Sn体系富Sn区液相限的研究

郑朝贵; 王志立; 潘锋; 应良春; 叶于浦   

  1. 北京大学化学系
  • 收稿日期:1986-03-07 修回日期:1986-10-20 发布日期:1987-08-15
  • 通讯作者: 应良春

AN INVESTIGATION ON LIQUIDUS OF Sn-RICH CORNER OF Cu-Zn-Sn SYSTEM

Zheng Chaogui; Wang Zhili; Pan Feng; Ying Liangchun; Ye Yupu   

  1. Department of Chemistry; Peking University
  • Received:1986-03-07 Revised:1986-10-20 Published:1987-08-15
  • Contact: Ying Liangchun

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Abstract: The liquidus of the Sn-rich range in the phase diagram of Cu-Zn-Sn system has been investigated by means of thermal analysis and X-ray diffraction method. It was found that there are five surfaces corresponding to the primary crystalliza- tion of Sn, η-Cu_6Sn_5, ε-Cu_3Sn, ε-CuZn_(~6), and η-Zn respectively and three invariant points: E, the ternary eutectic point, (90.8 Wt.%Sn, 0.2wt. %Cu; 190 ℃) and two ternary peritectic points P_1(91.3Wt.%Sn, 5.8Wt.%Cu; 358 ℃) and P_2(~0.2 Wt. %Cu, 96.3Wt. %Sn; 218 ℃) in the Sn-rich range. No ternary intermetallic compound was detected.