物理化学学报 >> 1987, Vol. 3 >> Issue (05): 539-543.doi: 10.3866/PKU.WHXB19870518
Abstract: In this paper, the author deduced the Gradation Rule of the Conjugated Homo- logs E=a+b/N from the Linear Rule of the Homologous Energy Factor E=a+b((2k-1)/k)sin(kπ/(2N+1)) and acquired a new Homologous Function E=a+b(2k-1)/(N+1/2), which is better than Gradation Rule of the Conjugated Homologs. Five formulas of Linear Rule resently reported were tested and compared by using 96 series of data of photo-electron spectroscopy and 159 series of data of electren spectroscopy. The author holds that the Linear Rule of the Homolgous Energy Factor is better.
孙玉坤. 同系规律的联系和比较[J]. 物理化学学报, 1987, 3(05): 539-543.
Sun Yukun. CONNECTION AND COMPARISON OF DIFFERENT FORMULAS OF HOMOLOGOUS RULE OF ORGANIC COMPOUNDS[J]. Acta Phys. -Chim. Sin., 1987, 3(05): 539-543.
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