物理化学学报 >> 1988, Vol. 4 >> Issue (04): 424-427.doi: 10.3866/PKU.WHXB19880420

研究简报 上一篇    下一篇

可逆反应的热静力学研究法

秦自明; 吴小平; 王瑞林; 邓郁   

  1. 四川大学化学系
  • 收稿日期:1987-01-13 修回日期:1987-07-02 发布日期:1988-08-15
  • 通讯作者: 秦自明

A THERMOSTATIC METHOD FOR REVERSIBLE REACTIONS

Qin Ziming; Wu Xiaoping; Wang Ruiling; Deng Yu   

  1. Department of Chemistry; Sichuan University; Chengdu
  • Received:1987-01-13 Revised:1987-07-02 Published:1988-08-15
  • Contact: Qin Ziming

Abstract: A thermostatic method for reversible reactions is derived in this paper. The method is suitable to reactions in which two reactants are ligand and univalent cation. This method has been used to study complex reaction of Dibenzo-18-Crown-6 and Na~+. The values of ΔH and K~(°-) calculated with this method are in agreement with those in literature.