物理化学学报 >> 1988, Vol. 4 >> Issue (06): 669-672.doi: 10.3866/PKU.WHXB19880621

研究简报 上一篇    

Fe(CO)5多光子解离和电离动力学

李书涛; 韩景诚; 刘厚祥; 李昭临; 吴存恺; 史济良; 李方琳   

  1. 中科院安徽光机所激光光谱学实验室; 中科院上海有机化学所
  • 收稿日期:1986-07-26 修回日期:1988-06-07 发布日期:1988-12-15
  • 通讯作者: 李书涛

MULTIPHOTON DISSOCIATION-IONIZATION DYNAMICS OF Fe(CO)5

Li Shutao; Han Jingcheng; Liu Houxiang; Li Zhaolin; Wu Cunkai;
Shi Jiliang; Li Fanglin   

  1. Laboratory of Laser Spectroscopy; Anhui Institute of Optics and Fine Mechanics; Academia Sinica
    Shanghai Institute of Organic Chemistry; Academia Sinica
  • Received:1986-07-26 Revised:1988-06-07 Published:1988-12-15
  • Contact: Li Shutao

Abstract: Multiphoton dissociation-ionization dynamics of Fe(CO)_5 were studied mass spectrometrically with a molecular beam and XeCl excimer laser. The results show that Fe(CO)_n~+ (n= 1,2,… ,5) and Fe_2(CO)_4~+ ions are formed mainly via ion-molecule reaction between Fe~+ and Fe(CO)_5 and dissociation following. A “ladder” model of Fe(CO)_5 photodissociation is presented in the paper.