物理化学学报 >> 1989, Vol. 5 >> Issue (02): 243-245.doi: 10.3866/PKU.WHXB19890224
Li Changming*; Zha Quanxin
The electrochemical behaviors of thionyl chloride reduction in 0.11 mol dm~(-3) SOCl_2+ 0.1 mol dm~(-3) LiA1CI_4/DMF solution were studied with disc microelectrodes. For the first time, satisfactory Tafel plot with slope very nearly to 120mV/decade was obtained from steady polarization curve of thionyl chloride reduction. By analysis of the Tafel plot, it is clear that the first electron transfer of thionyl chloride reduction is a totally irreversible. The exchange current density of the first electron transfer of thionyl chloride reduction is 9.0×10~(-7)A.cm~(-2), andα value very near to 0.5.
李长明;查全性. 亚硫酰氯阴极还原的半对数极化曲线[J]. 物理化学学报, 1989, 5(02): 243-245.
Li Changming*; Zha Quanxin. THE TAFEL PLOT OF THIONYL CHLORIDE REDUCTION[J]. Acta Phys. -Chim. Sin., 1989, 5(02): 243-245.
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