物理化学学报 >> 1989, Vol. 5 >> Issue (06): 760-764.doi: 10.3866/PKU.WHXB19890624

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Pd/Al2O3表面上活性位性质及其与加氢反应动力学参数间的关系

陈诵英   

  1. 中国科学院山西煤炭化学所
  • 收稿日期:1988-05-03 修回日期:1989-05-16 发布日期:1989-12-15
  • 通讯作者: 陈诵英

THE DEPENDENCE OF KINETICS PARAMETERS OF HYDROGENATION REACTION ON THE PROPERTIES OF ACTIVE SITES OF Pd/Al2O3

Chen Songying   

  1. Institute of Coal Chemistry; Academia Sinica Taiyuan
  • Received:1988-05-03 Revised:1989-05-16 Published:1989-12-15
  • Contact: Chen Songying

Abstract:

By dynamic technique, the dependence of adsorption and surface reaction rate coefficients for α-methyl styrene hydrogenation on the properties of active sites of Pd/Al_2O_3 catalyst was studied. The results showed that there were two kinds of active sites on the surface of Pd/Al_O_3. Their number N_t, active frequency AF and the number of active atoms in an active site m were obtained and their variations were also studied. The coefficients of adsorption equilibrium, overall reaction rate and adsorption and surface reaction rate coefficients for a single active site κ~*, κ_0~*, κ_0~* and κ_r were calculated. Their changes with Pd content were as same as that of active frequency AF except for κ_r and the change of κ_r was consistent with that of m value. In summary, the kinetic parameters of a catalytic reaction depend not only on the number of active sites, but also on some properties of the active site, such as AF and m value.