物理化学学报 >> 1990, Vol. 6 >> Issue (01): 103-106.doi: 10.3866/PKU.WHXB19900119

研究简报 上一篇    

镍基复合镀层对析氢反应的电催花活性

马凌;郭鹤桐;覃奇贤   

  1. 兰州大学化学系;天津大学应化系
  • 收稿日期:1988-06-27 修回日期:1989-04-07 发布日期:1990-02-15
  • 通讯作者: 马凌

The Electrocatalysis for Proton Reduction of Ni Based Composite Plating Layer

Ma Ling;Guo He-Tong;Tan Qi-Xian   

  1. Lanzhou University Chemistry Department;Tianjin University Applied Chemistry Department
  • Received:1988-06-27 Revised:1989-04-07 Published:1990-02-15
  • Contact: Ma Ling

Abstract: In this study, Ni-ZrO_2 and Ni-WC composite electrodes were prepared with the technique of composite electroplating, and used in the cathodic reduction reaction of H~+ in acid solution. The electrocatalytic properties and true surface area of the electrodes were determined by electrochemical and physical methods. It was found that the composite electrods had higher catalytic activity than pure Ni plated electrode for reduction reaction of H~+. The effect of content of the particles in the composite electrodes on the electrocatalytic property of the electrodes was discussed. Our results suggest that there is a possibility of preparing various new types composite electrode with electrocatalytic activities for certain redoxreaction system through the technique of composite electroplating by selecting proper materials.