物理化学学报 >> 1990, Vol. 6 >> Issue (05): 618-621.doi: 10.3866/PKU.WHXB19900520

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四钼簇合物[Mo4O4Cl2(μ3-O)2(o-CH3C6H4COO)6]性质与电子结构研究

郭纯孝; 黄启军; 孙春亭; 张恒彬; 刘晓勋; 杨帆; 董钢   

  1. 吉林大学化学系，长春
  • 收稿日期:1989-06-09 修回日期:1990-01-13 发布日期:1990-10-15
  • 通讯作者: 郭纯孝

Properties and Electronic Structures of Cluster [Mo4O4Cl2(μ3-O)2(o-CH3C6H4COO)6]

Guo Chun-Xiao; Huang Chun-Jun; Sun Chun-Ting; Zhang Heng-Bin; Liu Xiao-Xun; Yang Fan; Dong Gang   

  1. Department of Chemistry, Jilin University, Changchun
  • Received:1989-06-09 Revised:1990-01-13 Published:1990-10-15
  • Contact: Guo Chun-Xiao

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Abstract: UV spectra, IR spectra, Electronic oxidation-reduction properties and XPS spectrum of the tetramolybdenum cluster Mo_4O_4Cl_2(μ_3-O) (o-CH_3C_6H_4COO)_6 has been studied, and the electronic structure of the cluster has been interpreted with semiempirical quantum chemical calculation based on EHMO.