物理化学学报 >> 1992, Vol. 8 >> Issue (04): 438-440.doi: 10.3866/PKU.WHXB19920403

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一类新型硼氢阴离子BnH-m的激光产生

黄荣彬; 郑兰荪; 朱永宝; 张乾二   

  1. 固体表面物理化学国家重点实验室,厦门大学化学系,厦门 361005
  • 收稿日期:1992-01-03 修回日期:1992-04-03 发布日期:1992-08-15
  • 通讯作者: 郑兰荪

Generation of a New Type of Borane Anions with Laser Ablation

Huang Rong-Bin; Zheng Lan-Sun; Zhu Yong-Bao; Zhang Qian-Er   

  1. Department of Chemistry, Xiamen University, Xiamen 361005
  • Received:1992-01-03 Revised:1992-04-03 Published:1992-08-15
  • Contact: Zheng Lan-Sun

关键词: 硼烷, 桥式硼氢键, 激光等离子体质谱

Abstract: By laser ablation of NaBH_4 on a home-made instrument, four series of borane anions B_nH_m~- with formular of n=3k+1, m=5k+4; n=3k+2, m=5k+1; n=3k+2, m=5k+5; n=3k+3, m=5k+6 (k=0,1,2…) were observed at first time on recorded time-of-flight mass spectra with different ion intensities. From analysis of the mass spectra and calculate their possible topologies, a dragon-like structure was suggested for these new type of borane anions.

Key words: Borane, Bridged B-H bond, Laser plasma mass spectrometry