物理化学学报 >> 1992, Vol. 8 >> Issue (04): 558-562.doi: 10.3866/PKU.WHXB19920427

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电化学法测定几种稀土贮氢合金的热力学函数

周作祥; 何春红; 王正平; 王春明   

  1. 南开大学化学系，天津 300071
  • 收稿日期:1991-03-11 修回日期:1991-10-19 发布日期:1992-08-15
  • 通讯作者: 周作祥

The Determination of Thermodynamic Characteristics of Several Rare Earth Hydrogen-Storage Alloys by Electrochemical Method

Zhou Zuo-Xiang; He Chun-Hong; Wang Zheng-Ping; Wang Chun-Ming   

  1. Department of Chemistry, Nankai University, Tianjin 300071
  • Received:1991-03-11 Revised:1991-10-19 Published:1992-08-15
  • Contact: Zhou Zuo-Xiang

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关键词: 贮氢合金, 固-气吸放氢, 热力学函数, 电化学法

Abstract: The p—C—T curves of three kinds of hydrogen-storage alloys were examined by solid-gas phase hydrogen absorbing-desorbing and electrochemical method, the thermodynamic characteristics of each alloy were calculated by Van't Hoff equation. There is small difference between the results of the two methods at low temperatures but at high temperatures the difference is relatively large.

Key words: Hydrogen-storage alloy, Solid-gas absorbing-desorbing hydrogen, Thermodynamic function, Electrochemical method