物理化学学报 >> 1992, Vol. 8 >> Issue (05): 681-684.doi: 10.3866/PKU.WHXB19920521

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α-生育酚中性自由基的EPR考察

冯良波; 汪汉卿   

  1. 中国科学院兰州化学物理研究所，兰州 730000
  • 收稿日期:1991-06-05 修回日期:1991-11-22 发布日期:1992-10-15
  • 通讯作者: 冯良波

An EPR Study of DL-α-Tocopherol Neutral Radical

Feng Liang-Bo; Wang Han-Qing   

  1. Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000
  • Received:1991-06-05 Revised:1991-11-22 Published:1992-10-15
  • Contact: Feng Liang-Bo

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关键词: α-生育酚, 中性自由基, 电子顺磁共振

Abstract: The DL-α-tocopherol neutral radical (α-T) produced by the hydrogen abstraction of DL-α-tocopheral (α-TH) with di-tert-butylperoxide (DBPO), 2,2'-azo-(2,4-di-methyl-valeronitrile) (ADVN), γ-Al_2O_3 or SiO_2/Al_2O_3 has been studied by EPR spec-troscopy. From these experimental results, the mechanism of α-T radical generation is discussde.

Key words: DL-α-tocopherol, Neutral radical, EPR