物理化学学报 >> 1993, Vol. 9 >> Issue (02): 268-272.doi: 10.3866/PKU.WHXB19930224

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茂铁基多核配合物猝灭*Cr(bpy)3+3发光过程研究

夏旭兵; 段春迎; 朱龙根; 曹红; 游京晶   

  1. 南京大学配位化学研究所，南京 210008；江苏省食品发酵研究所，南京 210024
  • 收稿日期:1991-11-15 修回日期:1992-06-16 发布日期:1993-04-15
  • 通讯作者: 夏旭兵

Study on the Ferrocene-Containing Ploynuculi Metal Complexes Quenching Luminescence of *[Cr(bpy)3]3+

Xia Xu-Bing; Duan Chun-Ying; Zhu Long-Gen; Cao Hong; You Jing-Jing   

  1. Coordination Chemistry Institute, Nanjing University, Nanjing 210008; Food Frementation Institute of Jiangsu, Nanjing 210024
  • Received:1991-11-15 Revised:1992-06-16 Published:1993-04-15
  • Contact: Xia Xu-Bing

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关键词: Cr(bpy)3+3, 多核配合物, 猝灭过程, 电子转移和能量传递

Abstract: Ferrocene-containing ploynuclear metal complexes M(Fe-C(CH_3)=N N=CSSR)_2 (M=Ni~(2+), Cu~(2+), Zn~(2+), Pd~(2+), Co~(2+), Cd~(2+), R=CH_3, CH_2φ) have been synthesized and characterized by cyclic voltummetry. It has been found that this kind of complexes can quench the luminescence of [Cr(bpy)_3]~(3+) efficiencily. The Stern-Volmer plot is linear and yield the bimolecular quenching rate constants in order of 10~8～10~9 dm~3·mol~(-1)·s~(-1). The quenching process is carrid out through electron transfer and energy transfer mechanism.

Key words: Cr(bpy)3+3, Polynuclear complexes, Quenching process, Electron and energy transfer mechanisms