物理化学学报 >> 1993, Vol. 9 >> Issue (03): 299-301.doi: 10.3866/PKU.WHXB19930304

通讯 上一篇    下一篇

铝硫二元团簇的组分及其光解规律

史扬; 张南; 高振; 朱起鹤; 孔繁敖   

  1. 中国科学院化学研究所,分子反应动力学国家重点实验室,北京 100080
  • 收稿日期:1992-12-18 修回日期:1993-02-19 发布日期:1993-06-15
  • 通讯作者: 高振

A Primary Study for the Formation and Photodissociation of Aluminum Sulfide Cluster Ions

Shi Yang; Zhang Nan; Gao Zhen; Zhu Qi-He; Kong Fan-Ao   

  1. Institute of Chemistry, Chinese Academia Sinica, The State Key Laboratory of Molecular Reaction Dynamics, Beijing 100080
  • Received:1992-12-18 Revised:1993-02-19 Published:1993-06-15
  • Contact: Gao Zhen

关键词: 原子团簇, 光解, 结构稳定性, 激光溅射

Abstract: Binary cluster ions consisted of aluminum and sulfur(Al_nS_m~+, n up to 63, m up to 94) are produced by laser ablation of a mixture of aluminum powder and sulfur powder. It was found that the formed cluster ions have a uniform increment of Al_2 S_3 in the composition. The photodissociation of the mass-selected cluster ions also show a simple dissociation channel by loss of(Al_2S_3)_x (x=1 or 3). The structural features of the cluster ions have been discussed.

Key words: Atomic cluster, Photolysis, Structural stability, Laser ablation