物理化学学报 >> 1994, Vol. 10 >> Issue (02): 145-150.doi: 10.3866/PKU.WHXB19940211

研究论文 上一篇    下一篇

紫外激光诱导C60与M(CO)6(M=Cr, Mo, W)的配位反应

张杰, 林金谷, 王文华, 佘永柏, 傅克坚   

  1. 中国科学院物理研究所,北京 100080
  • 收稿日期:1992-10-05 修回日期:1993-03-06 发布日期:1994-02-15
  • 通讯作者: 张杰

UV Laser Induced Coordinative Reaction btween C60 and M(CO)6 (M=Cr, Mo and W)

Zhang Jie, Lin Jin-Gu, Wang Wen-Hua, She Yong-Bai, Fu Ke-Jian   

  1. Institute of Physics, Chinese Academy of Sciences, Beijing 100080
  • Received:1992-10-05 Revised:1993-03-06 Published:1994-02-15
  • Contact: Zhang Jie

摘要:

研究了用紫外激光(355 nm)诱导C_(60)与金属羰基化合物M(CO)_6(M=Cr;Mo,W)的配位反应,合成了具有C_(4υ)对称性的配位络合物(η~2-C_(60))M(CO)_5,并初步讨论了C_(60)与M(CO)_6反应的动力学过程.

关键词: C60, M(CO)6(M=Cr, Mo和W), 紫外激光, 配位反应

Abstract:

In this paper, laser induced coordinative reactions between C_(60) and M(CO)_6 (M=Cr, Mo and W) are carried out and complexes (η~2-C_(60)) M(CO)_5 are formed. The dymamics of reaction are also tentatively discussed.

Key words: C60,  , M(CO)6(M=Cr, Mo, W),  , UV laser, Coordinative reactions