物理化学学报 >> 1995, Vol. 11 >> Issue (02): 171-174.doi: 10.3866/PKU.WHXB19950215

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乙醇溶液中ZnO纳米粒子的形成机理研究

陈四海, 任新民   

  1. 中国科学院感光化学研究所|北京 100101
  • 收稿日期:1993-11-24 修回日期:1994-02-03 发布日期:1995-02-15
  • 通讯作者: 陈四海

Mechanism Study on the Formation of ZnO Nanoparticle in Ethanol Solution

Chen Si-Hai, Ren Xin-Min   

  1. Institute of Photographic Chemistry,Beijing 100101, P.R.China
  • Received:1993-11-24 Revised:1994-02-03 Published:1995-02-15
  • Contact: Chen Si-Hai

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关键词: 氧化锌, 纳米粒子, 半导体

Abstract:

The mechanism of the formation of ZnO nanoparticle by mixing zinc acetate and sodium hydroxide in ethanol solution was studied. It has been found that there are two pathways to obtain ZnO nanoparticle: one is a fast process which is characterized by the direct dehydration of Zn(OH)2 when Zn2+ is in excess; another is a slow process which is featured by the formation of [Zn(OH)4]2- complex and the subsequent nucleation of ZnO particle when OH- is in excess.

Key words: Zinc oxide, Nanoparticle, Semiconductor