物理化学学报 >> 1995, Vol. 11 >> Issue (04): 375-380.doi: 10.3866/PKU.WHXB19950418

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磷酰化肽链中电子转移的ESR研究

汪志勇, 张志成, 张曼维, 姚思德, 屠铁成, 林念芸, 张其锦   

  1. 中国科学技术大学化学系|合肥 230026|中国科学院上海原子核研究所辐射化学开放实验室|上海 201900|中国科学技术大学材料科学与工程系|合肥 230026
  • 收稿日期:1994-01-25 修回日期:1994-07-27 发布日期:1995-04-15
  • 通讯作者: 汪志勇

Research on Electron Transfer in Phosphorylated Peptide by ESR

Wang Zhi-Yong, Zhang Zhi-Cheng| Zhang Man-Wei, Yao Si-De, Tu Tie-Cheng, Lin Nian-Yun, Zhang Qi-Jin   

  1. Department of Chemical Physics,University of Science and Technology of China,Hefei 230026|Laboratory of Radiation Chemistry,Shanghai Institute of Nuclear Research,Shanghai 201800|Department of Material Science and Engineering,University of Science and Technology of China,Hefei 230026
  • Received:1994-01-25 Revised:1994-07-27 Published:1995-04-15
  • Contact: Wang Zhi-Yong

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关键词: 磷酰化肽, 电子转移, 顺磁共振

Abstract:

Electron transfer (ET) is an important elementary step of chemical reaction. Phosphorus is the center of energy expression in biological system. As a result, the research on the ET of phosphoryl and nonphosphoryl peptides is very important for us to understand the role of phosphorus in life and reveal the secrets of life. In this paper, the ET in some phosphoryl and nonphosphoryl peptides  are studied by ESR. It is observed that the electron transfers along the backbone of the peptide and that phosphoryl group takes part in the elementary process in the phosphoryl peptide first.

Key words: Phosphorylated peptide, Electron transfer, ESR