物理化学学报 >> 1996, Vol. 12 >> Issue (10): 865-869.doi: 10.3866/PKU.WHXB19961001

通讯    下一篇

Tl2O3/聚-N-乙烯基咔唑复合纳米线的研究

刘俊福,杨孔章,陆祖宏,丁德胜,吴海明   

  1. 山东大学胶体与界面化学研究所,济南 250100|东南大学国家教委分子与生物分子电子学开放实验室,南京210096
  • 收稿日期:1996-05-24 修回日期:1996-08-02 发布日期:1996-10-15
  • 通讯作者: 杨孔章

Studies on Ordered Composite Nanowire Arrays of Tl2O3/ Poly-Nvinylcarbazole

Liu Jun-Fu,Yang Kong-Zhang,Lu Zu-Hong,Ding De-Sheng,Wu Hai-Ming   

  1. Institute of Colloid and Interface Chemistry,Shandong University,Jinan 250100|National Laboratory of Molecular and Biomolecular Electronics,Southeast University,Nanjing 210096
  • Received:1996-05-24 Revised:1996-08-02 Published:1996-10-15
  • Contact: Yang Kong-Zhang

关键词: 纳米线, Tl2O3, 聚-N-乙烯基咔唑(EPVK), LB膜

Abstract:

Stable monolayers of electropolymerized poly-N-vinylcarbazole (EPVK) and arachidic acid(AA) are obtained on a subphase of alkaline Tl2O3 colloidal solutions. As revealed by the atomic force microscope, there is phase separation in the mixed LB monolayers. Transmission electron microscopic observations reveal that ordered arrays of composite Tl2O3/Epvk nanowires are formed in the mixed monolayers. Formation of the composite nanowire arrays is attributed to the ordered adsorption of Tl2O3 colloidal particles along the polycationic EPVK chains. The composite nanowire array is 3.2nm wide with a spacing of 2.7nm.The composite nanowire arrays can also be formed when pure EPVK is used. Composite LB multilayers of Tl2O3/EPVK nanowire arrays are prepared. The bilayer spacing is 5.54nm.The present study is of importance to the fabrication of inorganic semiconductor/functional polymer composite nanowires.

Key words: Nanowire, Thallic oxide, Poly-N-vinylcarbazole, LB film