物理化学学报 >> 1998, Vol. 14 >> Issue (02): 185-187.doi: 10.3866/PKU.WHXB19980218

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Cu-Cr-O体系复合氧化物的合成、结构非完整性与催化性能

孟宪平, 罗宁, 王颖霞, 李能, 林炳雄, 赵同复   

  1. 北京大学物理化学研究所，北京 100871|北京石油化工学院，北京 102600
  • 收稿日期:1997-05-26 修回日期:1997-09-22 发布日期:1998-02-15
  • 通讯作者: 孟宪平

Studies on the Synthesis,Structural Imperfection and catalytic Properties of Cu-Cr-O Composite Oxides

Meng Xiao-Ping, Luo Ning, Wang Ying-Xia, Li Neng, Lin Bing-Xiong, Zhao Tong-Fu   

  1. Institute of Physical Chemistry,Peking University,Beijing 100871|Beijing Petro-Chemical College,Beijing 102600
  • Received:1997-05-26 Revised:1997-09-22 Published:1998-02-15
  • Contact: Meng Xiao-Ping

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关键词: 尖晶石, 钢铁矿, CO催化氧化, 结构非完整性

Abstract:

A series of samples in Cu-Cr-O composite oxide system were synthesized by citrate complexation method. The catalytic activities of samples were evaluated using CO oxidation as test reaction, and structural imperfection was determined by XRD analysis. The results indicate that two phases coexisting under the preparative conditions result in structural imperfection of the samples, which leads to enhanced activities of Cu-Cr-O composite oxides. The catalytic activity for CO oxidation reaction increases with Cu3+ contents in the samples.

Key words: Spinel, Delafossite, CO catalytic oxidation, Structural imperfection