物理化学学报 >> 1998, Vol. 14 >> Issue (07): 669 -672 .doi: 10.3866/PKU.WHXB19980719

研究简报 上一篇    

AM1研究甲酰和苯甲酰叠氮的热分解反应

徐文媛, 刘够生, 彭以元, 洪三国   

  1. 江西师范大学化学系,南昌 330027
  • 收稿日期:1997-08-07 修回日期:1998-03-11 发布日期:1998-07-15
  • 通讯作者: 洪三国

AM1 Method Study of Thermolyses of Formacyl and Benzoyl Azides

Xu Wen-Yuan, Liu Gou-Sheng, Peng Yi-Yuan, Hong San-Guo   

  1. Department of Chemistry,Jiangxi University,Nanchang 330027
  • Received:1997-08-07 Revised:1998-03-11 Published:1998-07-15
  • Contact: Hong San-Guo

关键词: 酰基叠氮, 热分解, 过渡态, AM1方法

Abstract:

AM1 SCF calculations have been carried out to study thermolyses of formacyl and benzoyl azides. The results show that these thermolyses have several reaction routes yielding different products.

Key words: Acylazides, Thermal decompositions, Transition state, AM1 method