物理化学学报 >> 1999, Vol. 15 >> Issue (05): 454-457.doi: 10.3866/PKU.WHXB19990513
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陈宏善, 季生福, 牛建中, 谢宝汉, 李树本
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Chen Hong-Shan, Ji Sheng-Fu, Niu Jian-Zhong, Xie Bao-Han, Li Shu-Ben
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关键词: 无定型二氧化硅, α-方石英, 红外和喇曼光谱
Abstract:
By calculating commercial silica at 1500℃ or adding sodium oxalate and calcinating at 850℃, α-cristobalite was obtained. The Raman and IR spectra of amorphous silica and α-cristobalite were studied. The Raman and IR spectra showed obvious changes. While amorphous silica transformed to α-cristobalite. The peak positions and peak shape changed, and new vibration mode appeared in the crystal phase. For amorphous silica, the Raman spectrum has a broad band between 210-515 cm- 1 and two weak peaks at 793 and 966 cm -1. After phase transition, the broad band split into two strong peaks at 416 and 231 cm-1, and the positions of weak peaks changed. The IR spectrum of SiO2 has two strong peaks at about 1100 and 480 cm-1 and a weak peak at 800 cm-1. For α-cristobalite, a strong new peak appeared at 620 cm-1, and the adsorption at 800 cm-1 increased considerably. α-cristobalite also has two adsorption peaks in far-infrared.
Key words: Amorphous silica, α-cristobalite, IR and Raman spectroscopy
陈宏善, 季生福, 牛建中, 谢宝汉, 李树本. 无定型氧化硅转变为α-方石英的振动光谱[J]. 物理化学学报, 1999, 15(05): 454-457.
Chen Hong-Shan, Ji Sheng-Fu, Niu Jian-Zhong, Xie Bao-Han, Li Shu-Ben. Vibration Spectroscopy on Transformation of Amorphous Silica to α-cristobalite[J]. Acta Phys. -Chim. Sin., 1999, 15(05): 454-457.
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链接本文: http://www.whxb.pku.edu.cn/CN/10.3866/PKU.WHXB19990513
http://www.whxb.pku.edu.cn/CN/Y1999/V15/I05/454
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