物理化学学报 >> 2000, Vol. 16 >> Issue (11): 997-1002.doi: 10.3866/PKU.WHXB20001108

研究论文 上一篇    下一篇

WO3/TiO2纳米材料的制备及光催化性能

李芳柏, 古国榜, 李新军, 万洪富   

  1. 广东省生态环境与土壤研究所 广州 510650|华南理工大学化工学院 广州 510642
  • 收稿日期:2000-02-29 修回日期:2000-05-30 发布日期:2000-11-15
  • 通讯作者: 李芳柏 E-mail:fbli@soil.gd.cn

Preparation,Characterization and Photo-catalytic Behavior of WO3/TiO2 Nanopowder

 Li Fang-Bai, Gu Guo-Bang, Li Xin-Jun, Wan Hong-Fu   

  1. Guangdong Institute of Eco-Environment and Soil Science,Leyiju,Guangzhou 510650|College of Chemical engineering,South China University of Technology,Wushan,Guangzhou 510642
  • Received:2000-02-29 Revised:2000-05-30 Published:2000-11-15
  • Contact: Li Fang-Bai E-mail:fbli@soil.gd.cn

摘要:

采用溶胶-凝胶法制备WO3/TiO2复合纳米光催化剂,掺入WO3、TiO2锐钛矿101峰的相对强度、平均晶粒直径与颗粒直径均减小,比表面积增大;WO3掺入摩尔比分别为2%、5%、8%时,新的LRS峰位分别出现在797、967及969cm-1;在380-460nm范围内,WO3/TiO2的反射率减小,XPS分析表明,WO3/TiO2晶体中存在W6+、W5+、W4+、和Ti4+、Ti3+。以亚甲基兰的光催化降解为反应模型,掺入WO3后,光催化活性增强,掺入摩尔比为2%时,WO3/TiO2的光催化活性最高。还讨论了光催化活性与性质的关系。

关键词: 光催化, 二氧化钛, 三氧化钨, 复合半导体, 亚甲基兰

Abstract:

WO3/TiO2 samples were prepared by sol-gel process and characterized by means of XRD、LRS、TEM、DRS、BET、XPS.It has been shown that the mean crystal diameter and mean particle diameter of WO3/TiO2 samples decreased while the percent of anatase and specific surface area increased owing to the doping of WO3.New LRS peaks presented at 797,967 and 969cm-1,respectively,when the concentration of doped WO3 was 2%,5%and 8%.The reflectance percentate of WO3/TiO2 samples was less than that of pure TiO2 in the range of 380-460nm.The XPS fitting analyses showed that there were W6+、W5+、W4+ and Ti4+、Ti3+ in the lattice of WO3/TiO2.Being a model reaction,the photo-catalytic degradation of methylene blue was investigated in TiO2 and WO3/TiO2 nanopowder suspension irradiated by high-pressure mercury lamp.As a result,the addition of WO3 to TiO2 greatly enhanced its photo-catalytic behavior,and the optimum concentration of WO3 in TiO2 was 2%(molar percent).Moreover,the relationship between photo-activity and the physical and chemical properties of the samples have been discussed.

Key words: Photo-catalysis, Titanium dioxide, Tungsten oxide, Coupled semiconductor, Methylene blue