物理化学学报 >> 2004, Vol. 20 >> Issue (07): 745-748.doi: 10.3866/PKU.WHXB20040716

研究论文 上一篇    下一篇

环己烷催化氧化制取顺酐和醋酸的催化剂研究

张海洲;赵荣明;詹拥共;蔡炳新   

  1. 湖南大学化学化工学院,长沙　410082
  • 收稿日期:2004-01-07 修回日期:2004-03-22 发布日期:2004-07-15
  • 通讯作者: 蔡炳新 E-mail:cbx@hnu.cn

Investigation of VPO Catalyst Transforming Gaseous Cyclohexane into Maleic Anhydride and Acetic Acid

Zhang Hai-Zhou;Zhao Rong-Ming;Zhan Yong-Gong;Cai Bing-Xin   

  1. College of Chemistry and Chemical Engineering ,Hunan University，Changsha　410082
  • Received:2004-01-07 Revised:2004-03-22 Published:2004-07-15
  • Contact: Cai Bing-Xin E-mail:cbx@hnu.cn

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摘要： 为研究气态环己烷催化氧化制取顺酐及醋酸的新反应，采取不同的方法制备了系列固体VPO催化剂.借助XRD、FT-IR对催化剂进行了主体晶相确定，用氧化还原滴定方法测定了不同晶相催化剂中钒的平均氧化数.结合催化反应的活性评价，发现催化剂主体晶相、结晶度、活化气氛和催化剂的V4＋/V5＋比均对目标反应的催化活性产生影响，5种催化剂中以(VO)2P2O7晶相催化剂的活性为最高.

关键词: VPO催化剂, 环己烷, 主体晶相, 钒的平均氧化数, 表征

Abstract: In order to investigate the new reaction concerning the transformation of gas-cyclohexane into maleic anhydride and acetic acid, various solid VPO catalysts were prepared by different preparation methods. The main crystalline phase of the catalysts and the average oxidation value of vanadium in the catalysts were determined respectively by XRD、FT-IR and chemical titration. Experiment results revealed that the main crystalline phase, crystallization，activation ambience, and V4＋/ V5＋ ratio in the catalysts affected catalytic activity and selectivity. The catalysts whose main crystalline phase is (VO)2P2O7 possessed high crystallinity and feasible V4＋/ V5＋ ratio. (VO)2P2O7 calcinated in reaction ambience occupied higher selectivity.

Key words: VPO catalysts, Crystalline phase, Crystallization, Average oxidation value of vanadium, Characterization