物理化学学报 >> 2005, Vol. 21 >> Issue (02): 182-186.doi: 10.3866/PKU.WHXB20050214

研究论文 上一篇    下一篇

新型磁性Fe3O4/EDTA复合纳米粒子的制备及性能研究

姜炜;李凤生;陈令允;杨毅;楚建军   

  1. 南京理工大学国家特种超细粉体工程技术研究中心,南京　210094; 无锡肿瘤防治研究所,无锡　214062
  • 收稿日期:2004-07-20 修回日期:2004-09-22 发布日期:2005-02-15
  • 通讯作者: 杨毅 E-mail:yyi@nssperc.com

Preparation and Properties of Novel Magnetic Fe3O4/EDTA Nano-composite Particles

JIANG Wei;LI Feng-Sheng;CHEN Ling-Yun;YANG Yi;CHU Jian-Jun   

  1. National Special Superfine Powder Engineering Research Center, Nanjing University of Science ＆Technology, Nanjing　210094; Institute of Wuxi Tumor Prevention and Cure, Wuxi　214062
  • Received:2004-07-20 Revised:2004-09-22 Published:2005-02-15
  • Contact: YANG Yi E-mail:yyi@nssperc.com

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摘要： 采用氨羧络合剂EDTA对纳米磁性Fe3O4粒子进行表面改性,制备出能够螯合金属离子和放射性核素离子的磁性Fe3O4/EDTA复合纳米粒子.用X射线衍射、红外光谱、透射电子显微镜、光电子能谱、振动样品磁强计和原子吸收光谱对复合粒子进行了表观形貌、结构、磁学及螯合性能表征.结果表明,纳米磁性Fe3O4和EDTA之间能够有效地以化学键合方式进行复合.改性后,Fe3O4/EDTA纳米复合粒子可以对包括放射性金属离子在内的多种金属离子具有良好的络合效果.

关键词: 复合粒子, 磁性, Fe3O4, EDTA, 络合剂

Abstract: Fe3O4/EDTA nano-composite particles with capability of chelating general metal ions and radio-nuclide metal ions were prepared, and characterized by IR, XRD, XPS, TEM, VSM(vibrating sample magnetometer) and AAS(atomic absorption spectrometer).Chelating agent EDTA was used for the surface modification of Fe3O4 magnetic particles with 20 nm in size. The effects of temperature of preparation process on the crystal form and magnetization, and the capability of the Fe3O4/EDTA nano-composite particles to chelate metal ions were investigated. The results showed that (1) the magnetization of the composite particles prepared at 50～70 ℃ modification condition was equal to that of unmodified Fe3O4 nanometer particles;(2) the stability against oxidization of the Fe3O4/EDTA composite particles was improved owing to the modification of the Fe3O4 particles by EDTA;(3) the composite particles could chelate several general metal ions, such as Cu(Ⅱ)、Ca(Ⅱ)、Mg(Ⅱ) and Ni(Ⅱ),due to that the surface of the Fe3O4/EDTA composite particles was possessed of chelating function groups.

Key words: Composite particles, Magnetism, Fe3O4, EDTA, Chelating agent