物理化学学报 >> 2006, Vol. 22 >> Issue (12): 1484-1488.doi: 10.1016/S1872-1508(06)60076-4

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Co2+与BPPT络合反应动力学及动力学光谱法测定钴

BINGOL Haluk;ATALAY Tevfik   

  1. (Faculty of Education, Department of Chemistry, Selcuk University, Konya 42090, Turkey)
  • 收稿日期:2006-05-18 修回日期:2006-07-21 发布日期:2006-12-06
  • 通讯作者: BINGOL Haluk E-mail:hbingol@selcuk.edu.tr

Study of Kinetics of Complexation Reaction of Co2+ with 2-benzoylpyridine-4-phenyl-3-thiosemicarbazone and Kinetic-spectrophotometric Determination of Cobalt

BINGOL Haluk;ATALAY Tevfik   

  1. (Faculty of Education, Department of Chemistry, Selcuk University, Konya 42090, Turkey)
  • Received:2006-05-18 Revised:2006-07-21 Published:2006-12-06
  • Contact: BINGOL Haluk E-mail:hbingol@selcuk.edu.tr

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摘要： Kinetics of complexation reaction of Co2+ with 2-benzoylpyridine-4-phenyl-3-thiosemicarbazone (BPPT) was spectrophotometrically examined at 421 nm. The ligand that is developed for a simple kinetic-spectrophotometric determination of Co2+ is based on 1:2 complex formation between Co2+ and BPPT. The complexation reaction was carried out in ethanol-water medium at 25 ℃. Kinetic and activation parameters of the complexation reaction were calculated, and the rate equation and the reaction mechanism were proposed. The calibration graph is linear in the concentration range of 0.10～2.91 mg•L−1 for the tangent method. The species that caused interference were investigated.

关键词: Cobalt, Thiosemicarbazone, Kinetic study, Kinetic-spectrophotometric determination

Abstract: Kinetics of complexation reaction of Co2+ with 2-benzoylpyridine-4-phenyl-3-thiosemicarbazone (BPPT) was spectrophotometrically examined at 421 nm. The ligand that is developed for a simple kinetic-spectrophotometric determination of Co2+ is based on 1:2 complex formation between Co2+ and BPPT. The complexation reaction was carried out in ethanol-water medium at 25 ℃. Kinetic and activation parameters of the complexation reaction were calculated, and the rate equation and the reaction mechanism were proposed. The calibration graph is linear in the concentration range of 0.10～2.91 mg•L−1 for the tangent method. The species that caused interference were investigated.

Key words: Cobalt, Thiosemicarbazone, Kinetic study, Kinetic-spectrophotometric determination