物理化学学报 >> 2011, Vol. 27 >> Issue (02): 267-274.doi: 10.3866/PKU.WHXB20110217

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氟磷酸盐及正硅酸盐锂离子电池正极材料研究进展

张秋美1, 施志聪1,2, 李益孝3, 高丹1, 陈国华2, 杨勇3   

  1. 1. 大连理工大学化工学院, 精细化工国家重点实验室, 辽宁 大连 116012;
    2. 广州市香港科大霍英东研究院, 绿色产品及加工技术研究中心, 广州 511458;
    3. 厦门大学化学化工学院, 固体表面物理化学国家重点实验室, 福建 厦门 361005
  • 收稿日期:2010-07-29 修回日期:2010-09-20 发布日期:2011-01-25
  • 通讯作者: 施志聪, 杨勇 E-mail:zcshi@dlut.edu.cn, yyang@xmu.edu.cn
  • 基金资助:

    高等学校博士学科点专项科研基金(20090041120020)和中央高校基本科研业务费专项资金(DUT10JN06)资助项目

Recent Advances in Fluorophosphate and Orthosilicate Cathode Materials for Lithium Ion Batteries

ZHANG Qiu-Mei1, SHI Zhi-Cong1,2, LI Yi-Xiao3, GAO Dan1, CHEN Guo-Hua2, YANG Yong3   

  1. 1. State Key Laboratory for Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, Liaoning Province, P. R. China;
    2. Center for Green Products and Process Technologies, Guangzhou HKUST Fok Ying Tung Research Institute, Guangzhou 511458, P. R. China;
    3. State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
  • Received:2010-07-29 Revised:2010-09-20 Published:2011-01-25
  • Contact: SHI Zhi-Cong, YANG Yong E-mail:zcshi@dlut.edu.cn, yyang@xmu.edu.cn
  • Supported by:

    The project was supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China (20090041120020) and Foundamental Research Funds for the Central Universities, China (DUT10JN06).

摘要:

综述了用于锂离子电池的氟磷酸盐和正硅酸盐正极材料的研究现状, 重点对各种材料的结构及合成方法与性能的关系, 特别是对如何改善材料的电化学性能进行了总结和探讨. 展望了这两类锂离子电池正极材料的发展趋势.

关键词: 锂离子电池, 正极材料, 氟磷酸盐, 正硅酸盐

Abstract:

We review recent research on fluorophosphate and orthosilicate cathode materials for lithium ion batteries. Emphasis is placed on the relationship between structures, methods of preparation and properties of the cathode materials. We especially focus on factors leading to an improvement in their electrochemical performance. Trends of research into fluorophosphate and orthosilicate cathode materials are also discussed.

Key words: Lithium ion battery, Cathode material, Fluorophosphate, Orthosilicate

MSC2000: 

  • O646