层状双金属氢氧化物的剥离方法及其应用

doi:10.3866/PKU.WHXB20110826

摘要/Abstract

摘要：

层状双金属氢氧化物(LDHs)是由带结构正电荷的片层和层间阴离子有序组装而成的层状无机化合物, 近期其剥离研究受到关注. 剥离后的LDHs纳米片可被看做“无机高分子”, 具有纳米尺度的开放结构, 既可作为理论研究模型, 又可作为新型基元组装功能复合纳米结构或材料, 具有显著的应用潜力. 本文对LDHs的剥离方法、剥离产物的表征方法及其应用研究现状进行了综述, 并对今后的研究方向进行了展望.

关键词: 层状双金属氢氧化物, 类水滑石, 剥离, 甲酰胺

Abstract:

Layered double hydroxides (LDHs) are a class of layered inorganic materials that consist of structurally positively charged layers and exchangeable anions in the interlayer gallery for charge balance. The delamination of LDHs has attracted much attention in the last decade because it is an effective way for exposing the inner surfaces of the host layers. Delaminated nanosheets may be referred to as “macromolecules”, and they have opened nanostructures. They can be used as an ideal model system and as building blocks for various multilayer ultrathin films and functional nanocomposites. In this article, we outline the progress made regarding the delamination of LDHs and pose future challenges.

Key words: Layered double hydroxide, Hydrotalcite-like compound, Delamination, Formamide

MSC2000:

O648

聂宏骞, 侯万国. 层状双金属氢氧化物的剥离方法及其应用[J]. 物理化学学报, 2011, 27(08): 1783-1796.

NIE Hong-Qian, HOU Wan-Guo. Methods and Applications for Delamination of Layered Double Hydroxides[J]. Acta Phys. -Chim. Sin., 2011, 27(08): 1783-1796.

参考文献

(1) Goh, K. H.; Lim, T. T.; Dong, Z. L. Water Res. 2008, 42, 1343.
(2) Cavani, F.; Trifirò, F.; Vaccari, A. Catal. Today 1991, 11, 173.
(3) Angelo, V. Catal. Today 1998, 41, 53.
(4) Hou,W. G.; Zhang, C. G.; Sun, D. J.; Liang, X. L.;Wang, G. T. Chem. J. Chin. Univ. 1995, 16, 1292. [侯万国, 张春光, 孙德军, 梁晓丽, 王果庭. 高等学校化学学报, 1995, 16, 1292.]
(5) Kohjiyo, S.; Sato, T.; Nakayama, T.; Yamashita, S. Makromol. Chem. Rapid Commun. 1981, 2, 231.
(6) Reichle,W. T. J. Catal. 1980, 63, 295.
(7) Drezdon, M. A. Inorg. Chem. 1988, 27, 4628.
(8) Kumbhar, P. S.; Sanchez-Valente, J.; Lopez, J.; Figueras, F. Chem. Commun. 1998, No. 5, 535.
(9) Choudary, B. M.; Kantam, M. L.; Reddy, C. R. V.; Rao, K. K.; Figueras, F. J. Mol. Catal. A -Chem. 1999, 146, 279.
(10) Pérez-Ramírez, J.; Mul, G.; Kapteijn, F.; Moulijn, J. A. J. Mater. Chem. 2001, 11, 821.
(11) Kumbhar, P. S.; Sanchez-Valente, J.; Figueras, F. Chem. Commun. 1998, No. 10, 1091.
(12) Pérez, M. R.; Pavlovic, I.; Barriga, C.; Cornejob, J.; Hermosínb, M. C.; Ulibarri, M. A. Applied Clay Sci. 2006, 32, 245.
(13) Ulibarri, M. A.; Pavlovic, I.; Hermosin, M. C.; Cornejo, J. Appl. Clay Sci. 1995, 10, 131.
(14) Sood, A. Process for Removing Heavy Metal Ions from Solutions Using Adsorbents Containing Activated hydrotalcite. US Patent 4,752,397, Jan, 1988.
(15) Su, Y. L.; Hou,W. G.; Sun, D. J.; Liu, S. Y.; Zhang, C. G. Chem. J. Chin. Univ. 1999, 20, 1012. [苏延磊, 侯万国, 孙德军, 刘尚营, 张春光. 高等学校化学学报, 1999, 20, 1012.]
(16) Xia, C. Y.; Hou,W. G.; Sun, D. J.;Wang, G. T. Chin. J. Inorg. Chem. 1996, 12, 368. [夏春友, 侯万国, 孙德军, 王果庭. 无机化学学报, 1996, 12, 368.]
(17) Pinnavaia, T.; Constantino, V. R. L. Inorg. Chem. 1995, 34, 883.
(18) Costantino, U.; Casciola, M.; Massinelli, L.; Vivani, R. Solid State Ionics 1997, 97, 203.
(19) Rives, V.; Ulibarri, M. A. Coord. Chem. Rev. 1999, 181, 61.
(20) Dukka, P. K.; Puri, M. J. Phys. Chem. 1989, 93, 376.
(21) Nijs, H.; Clearfield, A.; Vansant, E. F. Microporous Mesoporous Mater 1998, 23, 97.
(22) Kanezaki, E. Mater. Res. Bull. 1999, 34, 1435.
(23) Rey, S.; Mérida-Robles, J.; Han, K. S.; Guerlou-Demourgues, L.; Delmas, C.; Duguet, E. Polym. Int. 1999, 48, 277.
(24) Millange, F.;Walton, R. I.; Lei, L. X.; O?Hare, D. Chem. Mater. 2000, 12, 1990.
(25) Prevot, V.; Forano, C.; Besse, J. P. Appl. Clay Sci. 2001, 18, 3.
(26) Crepaldi, E. L.; Pavan, P. C.; Valim, J. B. J. Mater. Chem. 2000, 10, 1337.
(27) Abend, S.; Bonnke, N.; Gutschner, U.; Lagaly, G. Colloid Polym. Sci. 1998, 276, 730.
(28) Itaya, K.; Chang, H. C.; Uchida, L. Inorg. Chem. 1987, 26, 624.
(29) Mousty, C.; Therias, S.; Forano, C.; Besse, J. P. J. Electroanal. Chem. 1994, 374, 63.
(30) Li, L. F.; Hou,W. G.; Jiao, Y. N.; Liu, C. X. Acta Phys. -Chim. Sin. 2004, 20, 459. [李丽芳, 侯万国, 焦燕妮, 刘春霞. 物理化学学报, 2004, 20, 459.]
(31) Liu, J. J.; Li, F.; Evans, D. G.; Duan, X. Chem. Commun. 2003, No. 4, 542.
(32) Ogawa, M.; Kuroda, K. Chem. Rev. 1995, 95, 399.
(33) Tagaya, H.; Ogata, S.; Nakano, S.; Kadokawa, J. I.; Karasu, M.; Chiba, K. J. Inclusio Phenom. Macrocyclic Chem. 1998, 31, 231.
(34) Robins, D. S.; Dutta, P. K. Langmuir 1996, 12, 402.
(35) Nakajima, H.; Ishino, S.; Masuda, H.; Shimosaka, T.; Nakagama, T.; Hobo, T.; Uchiyama, K. Chem. Lett. 2005, 34, 358.
(36) Ambrogi, V.; Fardella, G.; Grandolini, G.; Nocchetti, M.; Perioli, L. J. Pharm. Sci. 2003, 92, 1407.
(37) Tyner, K. M.; Schiffman, S. R.; Giannelis, E. P. J. Control. Release 2004, 95, 501.
(38) Sun, H.; Zhamg, H.; Evans, D. G.; Duan, X. Chin. Sci. Bull. 2004, 49, 2525. [孙辉, 张慧, Evans, D. G., 段雪. 科学通报, 2004, 49, 2525.]
(39) Gordijo, C. R.; Barbosa, C. A. S.; Ferreira, A. M. D. C.; Constantino, V. R. L.; Silva, D. O. J. Pharm. Sci. 2005, 94, 1135.
(40) Khan, A. I.; Lei, L. X.; Norquist, A. J.; O?Hare, D. Chem. Commun. 2001, No. 22, 2342.
(41) Hou,W. G.; Jin, Z. L. Colloid Polym. Sci. 2007, 285, 1449.
(42) Del Arco, M.; Gutiérrez, S.; Martín, C.; Rives, V.; Rocha, J. J. Solid State Chem. 2004, 177, 3954.
(43) Wei, M.; Shi, S.;Wang, J.; Li, Y.; Duan, X. J. Solid State Chem. 2004, 177, 2534.
(44) Del Arco, M.; Cebadera, E.; Gutiérrez, S.; Martín, C.; Montero, M. J.; Rives, V.; Rocha, J.; Sevilla, M. A. J. Pharm. Sci. 2004, 93, 1649.
(45) Xiao, R.;Wang,W. R.; Pan, L. L.; Zhu, R. R.; Yu, Y. C.; Li, H. P.; Liu, H.;Wang, S. L. J. Mater. Sci. 2011, 46, 2635.
(46) Choy, J. H.; Kwak, S. Y.; Park, J. S.; Jeong, Y. J.; Portier, J. J. Am. Chem. Soc. 1999, 121, 1399.
(47) Kwak, S. Y.; Jeong, Y. J.; Park, J. S.; Choy, J. H. Solid State Ionics 2002, 151, 229.
(48) Oh, J. M.; Kwak, S. Y.; Choy, J. H. J. Phys. Chem. Solids 2006, 67, 1028.
(49) Thyveetil, M. A.; Coveney, P. V.; Greenwell, H. C.; Suter, J. L. J. Am. Chem. Soc. 2008, 130, 4742.
(50) Goh, K. H.; Lim, T. T.; Dong, Z. L. Water Research 2008, 42, 1343.
(51) Adachi-Pagano, M.; Forano, C.; Besse, J. P. Chem. Commun. 2000, No. 1, 91.
(52) Leroux, F.; Adachi-Pagano, M.; Intissar, M.; Chauvière, S.; Forano, C.; Besse. J. P. Mater. Chem. 2001, 11, 105.
(53) Singh, M.; Ogden, M. I.; Parkinson, G. M.; Buckley, C. E.; Connolly. J. J. Mater. Chem. 2004, 14, 871.
(54) Venugopal, B. R.; Shivakumara, C.; Rajamathi, M. J. Colloid Interface Sci. 2006, 294, 234.
(55) Hibino, T.; Jones,W. J. Mater. Chem. 2001, 11, 1321.
(56) Hibino, T. Chem. Mater. 2004, 16, 5482.
(57) Guo, Y.; Zhang, H.; Zhao, L.; Li, G. D.; Chen, J. S.; Xu, L. J. Solid State Chem. 2005, 178, 1830.
(58) Wu, Q.; Olfsen, A.; Vistad, ?. B.; Roots, J.; Norby, P. J. Mater. Chem. 2005, 15, 4695.
(59) Wu, Q.; Sj?stad A. O.; Vistad, ?. B.; Knudsen, K. D.; Roots, J.; Pedersen, J. S.; Norby, P. J. Mater. Chem. 2007, 17, 965.
(60) He, S. H.; Pu, M.; Li, J. N.; He, J.; Evans, D. G. Acta Phys. -Chim. Sin. 2010, 26, 259. [何书珩, 蒲敏, 李军男, 何静, Evans, D. G. 物理化学学报, 2010, 26, 259.]
(61) Li, L.; Ma, R. Z.; Ebina, Y.; Iyi, N.; Sasaki, T. Chem. Mater. 2005, 17, 4386.
(62) Ma, R. Z.; Liu, Z. P.; Li, L.; Iyi, N.; Sasaki, T. J. Mater. Chem. 2006, 16, 3809.
(63) Iyi, N.; Matsumoto, T.; Kaneko, Y.; Kitamura, K. Chem. Lett. 2004, 33, 1122.
(64) Iyi, N.; Okamoto, K.; Kaneko, Y.; Matsumoto, T. Chem. Lett. 2005, 34, 932.
(65) Liu, Z. P.; Ma, R. Z.; Osada, M.; Iyi, N.; Ebina, Y.; Takada, K.; Sasaki, T. J. Am. Chem. Soc. 2006, 128, 4872.
(66) Liu, Z. P.; Ma, R. Z.; Ebina, Y.; Iyi, N.; Takada, K.; Sasaki, T. Langmuir 2007, 23, 861
(67) Hibino, T.; Kobayashi, M. J. Mater. Chem. 2005, 15, 653.
(68) Antonyraj, C. A.; Koilraj, P.; Kannan, S. Chem. Commun. 2010, 46, 1902.
(69) Jobbagy, M.; Regazzoni, A. E. J. Colloid Interface Sci. 2004, 275, 345.
(70) O?Leary, S.; O?Hare, D.; Seeley, G. Chem. Commun. 2002, No. 14, 1506.
(71) Zhao, Y.; Yang,W. D.; Xue, Y. H.;Wang, X. G.; Lin, T. J. Mater. Chem. 2011, 21, 4869.
(72) Hu, G.;Wang, N.; O’Hare, D.; Davis, J. Chem. Commun. 2006, No. 3, 287.
(73) Huang, S.; Cen, X.; Peng, H. D.; Guo, S. Z.Wang,W. Z.; Liu, T. X. J. Phys. Chem. B 2009, 113, 15225.
(74) Han, J. B.; Lu, J.;Wei, M.;Wang, Z. L.; Duan, X. Chem. Commun. 2008, No. 41, 5188.
(75) Han, J. B.; Yan, D. P.; Shi,W. Y.; Ma, J.; Yan, H.;Wei, M.; Evans, D. G.; Duan, X. J. Phys. Chem. B 2010, 114, 5678.
(76) Yan, D. P.; Lu, J.;Wei, M.; Han, J. B.; Ma, J.; Li, F.; Evans, D. G.; Duan, X. Angew. Chem. Int. Edit. 2009, 121, 3119.
(77) Yan, D. P.; Lu, J.; Ma, J.;Wei, M.; Li, F.;Wang, X. R.; Evans, D. G.; Duan, X. Langmuir 2010, 26, 7007.
(78) Yan, D. P.; Lu, J.;Wei, M.; Ma, J.; Li, F.; Evans, D. G.; Duan, X. Chem. Commn. 2009, No. 42, 6358.
(79) Yan, D. P.; Qin, S. H.; Chen, L.; Lu, J.; Ma, J.;Wei, M.; Evans, D. G.; Duan, X. Chem. Commn. 2010, 46, 8654.
(80) Yan, D. P.; Lu, J.; Chen, L.; Qin, S. H.; Ma, J.;Wei, M.; Evans, D. G.; Duan, X. Chem. Commn. 2010, 46, 5912.
(81) Yan, D. P.; Lu, J.; Ma, J.;Wei, M.; D. G.; Duan, X. Angew. Chem. Int. Edit. 2011, 123, 746.
(82) Shao, M. F.; Han, J. B.; Shi,W. Y.;Wei, M.; Duan, X. Electrochem. Commun. 2010, 12, 1077.
(83) Yang, D. B. The assembly of Delaminated Layered Double Hydroxides with Porcine pancreas Lipase. Master Dissertation, Beijing University of Chemical Technology, Beijing, 2007. [杨德宝. 剥离水滑石与猪胰脂肪酶的自组装[M]. 北京: 北京化工大学, 2007.]
(84) Huang, G. L.; Ma, S. L.; Zhao, X. H.; Yang, X. J.; Ooib, K. Chem. Commun. 2009, No. 3, 331.
(85) Huang, G. L.; Ma, S. L.; Zhao, X. H.; Yang, X. J.; Ooib, K. Chem. Mater. 2010, 22, 1870.
(86) Kang, H. L.; Huang, G. L.; Ma, S. L.; Bai, Y. X.; Ma, H.; Li, Y. L.; Yang, X. J.; J. Phys. Chem. C 2009, 113, 9157.
(87) Park, D. H.; Kim, J. E.; Oh, J. M.; Shul, Y. G.; Choy, J. H. J. Am. Chem. Soc. 2010, 132, 16735.

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