物理化学学报 >> 2009, Vol. 25 >> Issue (01): 191-200.doi: 10.3866/PKU.WHXB20090135

综述 上一篇    

界面扩张流变方法研究大分子与表面活性剂的相互作用

朱艳艳; 徐桂英   

  1. 山东大学胶体与界面化学教育部重点实验室, 济南 250100
  • 收稿日期:2008-09-08 修回日期:2008-10-09 发布日期:2008-12-31
  • 通讯作者: 徐桂英 E-mail:xuguiying@sdu.edu.cn

Investigation of Macromolecule/Surfactant Interaction by Interfacial Dilational Rheology Method

ZHU Yan-Yan; XU Gui-Ying   

  1. Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, Shandong University, Jinan 250100, P. R. China
  • Received:2008-09-08 Revised:2008-10-09 Published:2008-12-31
  • Contact: XU Gui-Ying E-mail:xuguiying@sdu.edu.cn

摘要: 结合本课题组的工作, 较系统地总结了近年来有关界面扩张流变技术在大分子/表面活性剂混合体系研究中的应用. 大量研究表明, 通过分析界面扩张粘弹性数据和界面弛豫过程的特征参数可以研究界面层微观性质, 从而阐明大分子/表面活性剂的相互作用机理, 这对实际生产和应用具有重要的指导意义.

关键词: 大分子, 表面活性剂, 界面扩张流变, 相互作用

Abstract: The applications of interfacial dilational rheology method in studying macromolecule/surfactant system were systematically summarized combing with our work. Many previous studies have indicated that this method can be used to probe the microcosmic property of interfacial layer. This is done by analyzing the interfacial dilational viscoelasticity and characteristic parameters of the interfacial relaxation process. The interaction mechanism between macromolecule and surfactant could thus be investigated. The method can be applied in practice.

Key words: Macromolecule, Surfactant, Interfacial dilational rheology, Interaction

MSC2000: 

  • O648
[11] 张涛,仇运广,罗启超,程曦,赵丽芬,严昕,彭浡,蒋华良,阳怀宇. 钙离子和镁离子浓度变化对磷脂酰乙醇胺-磷脂酰甘油双分子层膜的影响[J]. 物理化学学报, 2019, 35(8): 840 -849 . [12] 韩萌茹,周亚男,周旋,储伟. 通过g-C3N4担载MNi12 (Fe, Co, Cu, Zn)纳米团簇调节甲烷化[J]. 物理化学学报, 2019, 35(8): 850 -857 . [13] 谢文,何欢,董家新,郭清莲,刘义. 桑色素与血清白蛋白相互作用热力学行为[J]. 物理化学学报, 2019, 35(7): 725 -733 . [14] 罗思琪,王美娜,赵微微,王毅琳. 表面活性剂与叶酸的相互作用及其对光氧化降解的影响[J]. 物理化学学报, 2019, 35(7): 766 -774 . [15] 刘恒昌,冯玉军. CO2诱导的五嵌段非离子共聚物与阴离子氟碳表面活性剂的相互作用[J]. 物理化学学报, 2019, 35(4): 408 -414 .