物理化学学报 >> 2008, Vol. 24 >> Issue (12): 2327-2330.doi: 10.3866/PKU.WHXB20081230

研究简报 上一篇    下一篇

添加剂对染料敏化太阳电池电解质性能的影响

史成武, 葛茜, 李兵, 桃李, 刘清安   

  1. 合肥工业大学化学工程学院, 合肥 230009
  • 收稿日期:2008-07-01 修回日期:2008-09-18 发布日期:2008-12-04
  • 通讯作者: 史成武 E-mail:shicw506@mail.hf.ah.cn

Influence of Additives on the Performance of Electrolytes in Dye-Sensitized Solar Cells

SHI Cheng-Wu, GE Qian, LI Bing, TAO Li, LIU Qing-An   

  1. School of Chemical Engineering, Hefei University of Technology, Hefei 230009, P. R. China
  • Received:2008-07-01 Revised:2008-09-18 Published:2008-12-04
  • Contact: SHI Cheng-Wu E-mail:shicw506@mail.hf.ah.cn

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摘要： 以N-甲基咪唑、苯并咪唑、叔丁基吡啶和离子液体1-甲基-3-乙基咪唑三氟乙酸盐(EMITA)作为染料敏化太阳电池(DSCs)电解质溶液中的添加剂, 使用超微电极通过循环伏安法研究其对液体电解质中I-3和I-氧化还原行为的影响, 通过电化学阻抗谱研究了上述四种添加剂对Pt电极电解质界面的影响. 结果表明, 添加剂EMITA的加入使I-3在电解质中的扩散系数减小, Pt电极电解质界面上的界面传输电阻Rct增大, 电解质的电阻降低; 光伏性能测试表明, EMITA的添加提高了DSCs的开路电压和填充因子, 其DSCs的光电转换效率达到了5.72%.

关键词: 添加剂, 染料敏化太阳电池, Pt对电极, 电化学阻抗谱, 超微电极

Abstract: The influence of N-methylimidazole, benzimidazole, 4-tert-butylpyrdine and 3-ethyl-1-methyl-limidazoliumtrifluoroacetate (EMITA) on apparent diffusion coefficients of I-3 and I- in the electrolyte and the Pt counter electrode electrolyte interface was investigated by ultramicroelectrode and electrochemical impedance spectroscopy. The apparent diffusion coefficient of I-3 in the electrolyte decreased and charge transfer resistance at the Pt counter electrode electrolyte interface increased after the additives were added. The resistance of electrolytes decreased after addition of EMITA. A comparison of the photovoltaic performance of dye-sensitized solar cells (DSCs) containing the additives was undertaken. The additive EMITA increased the open voltage and the fill factor, and the efficiency of dye-sensitized solar cells was up to 5.72%.

Key words: Additive, Dye-sensitized solar cell, Pt counter electrode, Electrochemical impedance spectroscopy, Ultramicroelectrode

MSC2000: 

  • O646