物理化学学报 >> 1988, Vol. 4 >> Issue (01): 74-76.doi: 10.3866/PKU.WHXB19880114

研究简报 上一篇    下一篇

Bi和O2(1g)的化学发光研究

王守志; 刘仁章   

  1. 中国科学院大连化学物理研究所
  • 收稿日期:1986-07-21 修回日期:1987-04-08 发布日期:1988-02-15
  • 通讯作者: 王守志

STUDIES ON CHEMILUMINESCENT REACTION OF Bi+O2(1g)

Wang Shouzhi*; Liu Renzhang   

  1. Dalian Institute of Chemical Physics; Academia Sinica
  • Received:1986-07-21 Revised:1987-04-08 Published:1988-02-15
  • Contact: Wang Shouzhi

Abstract: The emission spectra of BiO has been first obtained by studying the reaction: Bi+O_2(~1△_g)in the atomic-beam apparatus. 22 new bands has been obtained from the emission spectra of BiO (A ~2Π_g) which are attributed to the collisional energy transfer process of BiO(X,v)+O_2(b ~1Σ_g~+). The O_2(b ~1Σ_g~+) is produced by the following process: O_2(~1△_g)+O_2(~1△_g)→O_2(b ~1Σ_g~+)+O_2(X ~3Σ_g~-).