物理化学学报 >> 1988, Vol. 4 >> Issue (06): 566-571.doi: 10.3866/PKU.WHXB19880602

研究论文 上一篇    下一篇

配位场弱场方案的酉群方法(dN离子)

文振翼; 王育邠; 豆育升; 刘朝萌   

  1. 西北大学现代物理所; 西北大学化学系
  • 收稿日期:1987-04-01 修回日期:1987-08-31 发布日期:1988-12-15
  • 通讯作者: 文振翼

THE UNITARY GROUP APPOACH (UGA) TO THE WEAK FIELD MODEL OF A LIGAND FIELD (dN IONS)

Wen Zhenyi*; Wang Yubin; Dou Yusheng; Liu Zhaomeng   

  1. Institute of Medern Physics & Department of Chemistry; Northwest University
  • Received:1987-04-01 Revised:1987-08-31 Published:1988-12-15
  • Contact: Wen Zhenyi

摘要: 本文用酉群方法(UGA)处理d壳层的弱配位场方案, 着重讨论了如何构成与群链U(5)>SU(5)>SO(3)>G匹配的对称函数。这些函数是用Lie代数方法构成,并且用U(5)群的Gelfand态表示。

Abstract: This paper deals with the weak ligand field of d-shell by use of the unitary group approach (UGA). It specially discusses how to construct symmetry functions adapted to the group chain U(5)>SO(5)>SO(3)>G. The functions are built up using the Lie algebraic technique and expressed in terms of Gelfand states of the (5) group.