物理化学学报 >> 1988, Vol. 4 >> Issue (06): 617-623.doi: 10.3866/PKU.WHXB19880610

研究论文 上一篇    下一篇

共轭与非共轭不饱和酯的振动光谱及其EHMO研究

赵冰; 刘举正; 梁映秋; 唐敖庆   

  1. 吉林大学理论化学研究所 长春
  • 收稿日期:1987-05-09 修回日期:1987-12-14 发布日期:1988-12-15
  • 通讯作者: 刘举正

STUDIES ON VIBRATION SPECTRA AND EHMO FOR CONJUGATION AND UNCONJUGATION UNSATURATED ESTER

Zhao Bing; Liu Juzheng*; Liang Yingqiu; Tang Aoqing   

  1. Institute of Theoretical Chemistry; Jilin University; Chang Chun
  • Received:1987-05-09 Revised:1987-12-14 Published:1988-12-15
  • Contact: Liu Juzheng

摘要: 用FT-IR、Laser Raman光谱和EHMO计算研究了β-羟基酯脱水反应, 发现反应产物α、β-烯酯和β、γ-烯酯两类共轭与非共轭构异体的分布, 主要取决于β-碳上的取代甲基超共轭效应, 该反应是受动力学控制的。

Abstract: Tracing out dehydrated reaction of β-hydroxy ester by FT-IR, luster Raman spectroscopy and EHMO calculation,it is found that the distribution for products, α,β-and, β, γ-unsaturated ester is dependent on super-conjugation of substitutedm ethyl on β-carbon. And it has been proved that the reaction examined is akinetic control.