物理化学学报 >> 1987, Vol. 3 >> Issue (04): 401-406.doi: 10.3866/PKU.WHXB19870413

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正己烷—TBP体系的光化学研究

潘宪明; 吴季兰   

  1. 北京大学技术物理系
  • 收稿日期:1986-04-05 修回日期:1986-11-07 发布日期:1987-08-15

THE STUDY OFT THE PHOTOCHEMISTRY OF n-HEXANE—TBP BINARY SYSTEM

Pan Xianming; Wu Jilan   

  1. Department of Technical Physics; Peking University
  • Received:1986-04-05 Revised:1986-11-07 Published:1987-08-15

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摘要： 用低压汞灯照射, 研究了n-C_6H_(14)—TBP体系的光化学反应。通过与γ辐解结果对比和动力学分析, 证实了γ辐解n-C_6H_(14)—TBP体系中, 激发能转移是能量传递的主要形式, 并讨论了亚激电子在能量传递中的作用。

Abstract: The photochemistry of n-hexane—TBP binary system under UV irradiation of low pressure mercury lamp has been investigated. It has been found that the excited energy transfer is the main process of energy transfer in this system under γ irradiation by comparing with the results of photo-decomposition. The contribution of subexcited electron in the energy transfer of γ irradiation was discussed.