物理化学学报 >> 1987, Vol. 3 >> Issue (05): 551-554.doi: 10.3866/PKU.WHXB19870521

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聚N-乙烯咔唑与硝基芴酮类在不同溶剂中形成的电荷转移复合物

李桂芳; 赵扬; 刘昌炎   

  1. 中国科学院化学研究所 北京
  • 收稿日期:1986-04-09 修回日期:1986-11-25 发布日期:1987-10-15

THE CHARGE-TRANSFER COMPLEXES OF POLY (N-VINYL-CARBAZOLE) AND NITROFLUORENONES IN DIFFERENT SOLVENTS

Li Guifang; Zhao Yang; Liu Changyan   

  1. Institute of Chemistry; Academia Sinica; Beijing
  • Received:1986-04-09 Revised:1986-11-25 Published:1987-10-15

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Abstract: The charge-transfer complexes of poly(N-vinylcarbazole) (Mn=7200) and nitro- fluorenones were studied with VPO in different solvents. The relationship between equilibrium constant and solvent dipole moment was examined. The results obtained from polymer and model compound were compared, and the reason of their difference was explained. The relationship between the equilibrium constant and the molecular weight was given:
InK_(CT)=InK_(CT)~∞+2M_0/M(InK°-InK~∞)