物理化学学报 >> 1987, Vol. 3 >> Issue (06): 621-625.doi: 10.3866/PKU.WHXB19870612

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某些铜(Ⅱ)-酸性磷(膦)酸酯配合物的固态和低温下的ESR波谱研究

陈德余; 徐元植; 周澄明   

  1. 浙江大学化学系 杭州 中国科学院上海有机化学研究所
  • 收稿日期:1986-07-21 修回日期:1987-07-15 发布日期:1987-12-15

ESR SPECTRA STUDY OF SOME COPPER (Ⅱ)-ACIDIC PHOSPHATES (PHOSPHONATES) COMPLEXES IN SOLID STATE AND AT LOW TEMPERATURE

Chen Deyu; Xu Yuanzhi; Zhou Chengming   

  1. Department of Chemistry; Zhejiang University; Hangzhou
    Shanghai Institute of Organic Chemistry; Academia Sinica
  • Received:1986-07-21 Revised:1987-07-15 Published:1987-12-15

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摘要： 本文考察了六种酸性磷(膦)酸酯铜(Ⅱ)配合物的室温固态ESR波谱, 并测得它们在四氢呋喃中在低温下ESR波谱参数, 计算了这类配合物的键参数和约化能级差, 讨论了它们的成键特性, 指出: 这类配合物中平面内σ-配键是起主要作用的, 而平面内的π-配键的成键作用也不能忽视。

Abstract: In the present paper ESR spectra of six acidic phosphates (phosphonates) co- pper (Ⅱ) complexes in solid state at room temperature have been examined, and their ESP spectral parameters in THE at low temperature have been determined. The bonding parameters and difference of reducible level of these complexes were calculated. The bonding characterization of these copper (Ⅱ) complexes were dis- cussed. The result shows that the in-plane σ-bond in these complexes plays an important role, but the action of in-plane π-bond on bonding of these complexes may not be also neglected.