物理化学学报 >> 1985, Vol. 1 >> Issue (06): 575-578.doi: 10.3866/PKU.WHXB19850612

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R、S双[N-(5-氯邻羟苯亚甲基)-α-苯乙胺]合钯(Ⅱ)的晶体结构及分子绝对构型

徐筱杰; 关烨弟; 尚振海; 关玥; 唐有祺   

  1. 北京大学化学系
  • 收稿日期:1985-01-03 修回日期:1985-03-16 发布日期:1985-12-15

THE CRYSTAL STRUCTURE AND MOLECULAR ABSOLUTE CONFIGURATIONS OF BIS [N-(5-CHLORO-OXID-BENZYLIDENE)-α-PHENYLETHYLAMINE] PALLADIUM(Ⅱ)

Xu Xiaojie; Guan Yedi; Shang Zhenhai; Guan Yue; Tang Youqi   

  1. Department of Chemistry, Peking University
  • Received:1985-01-03 Revised:1985-03-16 Published:1985-12-15

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Abstract: The title compound crystallizes in orthorhombic crystal system with space group P 2_12_12_1, α=0.8983(4) nm, b=1.7538(9) nm, c=1.7603(16) nm and z=4. The crystal structure were solved by direct method. Molecular absolute configurations for two enantiomeric structures were determined by anomalous scattering of Pd~(++) for CuKα radiation. The final R factors are 0.050 for R-(+)-structureand 0.051 for S-(-)-structure.