物理化学学报 >> 2007, Vol. 23 >> Issue (08): 1157-1162.doi: 10.1016/S1872-1508(07)60060-6

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Fe修饰多壁碳纳米管电极高效产H2O2

傅坚亮; 张兴旺; 雷乐成   

  1. 浙江大学环境污染控制技术研究所, 杭州 310028
  • 收稿日期:2007-03-21 修回日期:2007-04-16 发布日期:2007-08-03
  • 通讯作者: 雷乐成 E-mail:lclei@zju.edu.cn

Fe-modified Multi-walled Carbon Nanotube Electrode for Production of Hydrogen Peroxide

FU Jian-Liang; ZHANG Xing-Wang; LEI Le-Cheng   

  1. Institute of Environmental Pollution Control Technologies, Zhejiang University, Hangzhou 310028, P. R. China
  • Received:2007-03-21 Revised:2007-04-16 Published:2007-08-03
  • Contact: LEI Le-Cheng E-mail:lclei@zju.edu.cn

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摘要： 为提高电芬顿(Electro-Fenton)体系H2O2的产率, 制备了多壁碳纳米管(MWNT)电极, 并与石墨/气体扩散(GDC)电极进行了比较. 结果表明, MWNT电极H2O2产率高于GDC电极. 采用电沉积方法, 制备了Fe修饰MWNT(Fe-MWNT)电极, 发现Fe对MWNT电极的修饰不仅可以提高体系的H2O2产率, 而且电流效率可以提高8%左右, 与GDC电极的电流效率接近. Fe-MWNT电极有望成为一种新型的阴极材料应用于Electro-Fenton体系中.

关键词: 多壁碳纳米管, H2O2, Fe修饰, 电芬顿体系

Abstract: To improve the production efficiency of hydrogen peroxide in Electron-Fenton system, multi-walled carbon nanotube (MWNT) electrode was prepared. Compared with graphite/gas diffusion cathode (GDC) electrode, the MWNT electrode showed higher hydrogen peroxide production efficiency. The Fe-modified MWNT (Fe-MWNT) electrode was prepared using the electro chemical deposition method. The as prepared Fe-MWNT electrode showed higher hydrogen peroxide production efficiency, and the average current efficiency increased by 8%after Fe modification in comparison with the unmodified MWNT. The average current efficiency of the Fe-MWNT electrode was close to that of the GDCelectrode. The Fe-MWNT electrode is a novel promising cathode material for application in the Electron-Fenton system.

Key words: Multi-walled carbon nanotubes, Hydrogen peroxide, Fe-modification, Electro-Fenton system

MSC2000: 

  • O646