物理化学学报 >> 1985, Vol. 1 >> Issue (04): 378-383.doi: 10.3866/PKU.WHXB19850413

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二[1,2-二硫代(3,5-二硫杂-4-硫酮)戊烯]铜和锌络合物的四丁基胺盐的晶体结构

王洪辉; 朱道本; 竺迺珏; 傅亨   

  1. 中国科学院化学研究所
  • 收稿日期:1984-12-25 修回日期:1985-02-09 发布日期:1985-08-15

CRYSTAL STRUCTURES OF TETRABUTYLAMMONIUM BIS(ISOTRITHIONEDITHIOLATO) COPPER (Ⅱ) AND ZINC (Ⅱ)

Wang Honghui; Zhu Daoben; Zhu Naijue; Fu Heng   

  1. Institute of Chemistry, Academia Sinica, Beijing
  • Received:1984-12-25 Revised:1985-02-09 Published:1985-08-15

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Abstract: The crystal structures of the title compounds have been determined from threedimensional intensity measured on a R3m/E four circle diffractometer. The crystallographic data are listed in Table 1.
The structure of [N(C_4H_9)_4]_2[Cu(S_5C_3)_2] was solved by trial and error using isomophous [N(C_4H_9)_4]_2[Pd(S_5C_3)_2] crystal data. The structure of [N(C_4H_9)_4]_2[Zn(S_5C_3)_2] was solved by direct method using SHELXTL program system. The H atom coordinates were calculated geometrically. The refinement of coordinates and anisotropic thermal parameters was performed by “blocked cascade” least squares to R=0.044 for Cu(II) compound and R=0.057 for Zn(II) compound calculated on the basis of 2424 and 1219 independent reflections respectively. All the numerical calculations were carried out on a Eclipse/S_(140) computer with programs of R3m/E system.
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