物理化学学报 >> 1989, Vol. 5 >> Issue (05): 613-620.doi: 10.3866/PKU.WHXB19890522

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稀土环己烷酸配合物合成及振动光谱研究

张树功; 倪嘉缵; 梁映秋; 赵文运; 张元福; 徐蔚清   

  1. 中国科学院长春应用化学研究所; 吉林大学理论化学研究所
  • 收稿日期:1988-01-03 修回日期:1988-11-28 发布日期:1989-10-15
  • 通讯作者: 张树功

SYNTHESIS AND VIBRATIONAL SPECTRUM STUDIES OF RARE EARTH COMPLEXES WITH CYCLOHEXANE CARBOXYLIC ACID

Zhang Shugong*; Ni Jiazuan; Liang Yingqiu; Zhao Wenyun; Zhang Yunfu; Xu Weiqing   

  1. Changchun Institute of Applied Chemistry; Academia Sinia; Theoretical Chemistry Institute; Jilin University
  • Received:1988-01-03 Revised:1988-11-28 Published:1989-10-15
  • Contact: Zhang Shugong

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Abstract: The solid state complexes of trivalent lanthanid, yttrium and scandium with cyclohexane carboxylic acid have been isolated and characterized by IR and Raman spectroscopy. It was found that there are only chelated carboxylate groups in the scandium complex and that there are the chelated, bridged and chelate-bridged carboxylate groups in other rare earth complexes. The former is a mononuclear complex and the latter is a polynuclear polymer. The RE—O coordinate bonds possess the characters of convalent ionic bond.